Phosphate-mediated interconversion of Ribo- and Arabino-configured prebiotic nucleotide intermediates. Powner, M. W. & Sutherland, J. D. Angewandte Chemie - International Edition, 49(27):4641–4643, 2010.
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(Represented Chemical Equation) Flipping stereochemistry: Inorganic phosphate catalyzes the interconversion of ribose and arabinose aminooxazolines, suggesting that the prebiotic synthesis of enantiopure pyrimidine ribonucleotides might have involved a single stereoinversion at Cl′ and a double stereoinversion at C2′. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
@article{Powner2010b,
abstract = {(Represented Chemical Equation) Flipping stereochemistry: Inorganic phosphate catalyzes the interconversion of ribose and arabinose aminooxazolines, suggesting that the prebiotic synthesis of enantiopure pyrimidine ribonucleotides might have involved a single stereoinversion at Cl′ and a double stereoinversion at C2′. {\textcopyright} 2010 Wiley-VCH Verlag GmbH {\&} Co. KGaA, Weinheim.},
author = {Powner, Matthew W. and Sutherland, John D.},
doi = {10.1002/anie.201001662},
issn = {14337851},
journal = {Angewandte Chemie - International Edition},
keywords = {Chirality,Homogeneous catalysis,Nucleotides,Phosphate,Prebiotic chemistry},
number = {27},
pages = {4641--4643},
pmid = {20491113},
title = {{Phosphate-mediated interconversion of Ribo- and Arabino-configured prebiotic nucleotide intermediates}},
volume = {49},
year = {2010}
}

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