Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides. Pérez-Omil, J., Bernal, S., Calvino, J., Hernández-Garrido, J., Mira, C., Rodríguez-Luque, M., Erni, R., & Browning, N. Chemistry of Materials, 17(17):4282–4285, Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Cádiz, Spain, 2005. Paper abstract bibtex The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.
@article{Perez-Omil2005,
abstract = {The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.},
address = {Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 C\'{a}diz, Spain},
annote = {Cited By (since 1996): 20
Export Date: 15 January 2013
Source: Scopus
CODEN: CMATE
doi: 10.1021/cm050976g
Language of Original Document: English
Correspondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 C\'{a}diz, Spain; email: jose.calvino@uca.es
References: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10;
Izu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107;
Baker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodr\'{\i}guez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149;
Fornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Mart\'{\i}nez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149;
Montini, T., Ba\~{n}ares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1;
Montini, T., Hickey, N., Fornasiero, P., Graziani, M., Ba\~{n}ares, M.A., Mart\'{\i}nez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157;
Kishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94;
Bernal, S., Botana, F.J., Calvino, J.J., L\'{o}pez Cartes, C., P\'{e}rez-Omil, J.A., Rodr\'{\i}guez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135;
Stadelmann, P., (1987) Ultramicroscopy, 21, p. 131;
Kirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York;
Col\'{o}n, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717;
Vidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93;
Torng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505;
Masui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240;
Pennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565;
Browning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229;
Zhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317;
Mamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. B, 107, p. 13007},
author = {P\'{e}rez-Omil, JA. and Bernal, S. and Calvino, JJ. and Hern\'{a}ndez-Garrido, JC. and Mira, C. and Rodr\'{\i}guez-Luque, MP. and Erni, R. and Browning, ND.},
issn = {08974756 (ISSN)},
journal = {Chemistry of Materials},
keywords = {Age hardening,Ceria-Zirconia mixed oxides,Crystal lattices,Heat treatment,High resolution electron microscopy,High-angle annular dark field (HAADF) scanning ele,Positive ions,Scanning electron microscopy,Sublattices,Thermal ageign,Zirconia},
number = {17},
pages = {4282--4285},
title = {{Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides}},
url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885&partnerID=40&md5=b0a8ec860259046c6e39ce4a7f28040e},
volume = {17},
year = {2005}
}
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The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.","address":"Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Cádiz, Spain","annote":"Cited By (since 1996): 20 Export Date: 15 January 2013 Source: Scopus CODEN: CMATE doi: 10.1021/cm050976g Language of Original Document: English Correspondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Cádiz, Spain; email: jose.calvino@uca.es References: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10; Izu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107; Baker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodríguez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149; Fornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Martínez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149; Montini, T., Bañares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1; Montini, T., Hickey, N., Fornasiero, P., Graziani, M., Bañares, M.A., Martínez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157; Kishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94; Bernal, S., Botana, F.J., Calvino, J.J., López Cartes, C., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135; Stadelmann, P., (1987) Ultramicroscopy, 21, p. 131; Kirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York; Colón, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717; Vidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93; Torng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505; Masui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240; Pennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565; Browning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229; Zhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317; Mamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. 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The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.},\naddress = {Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 C\\'{a}diz, Spain},\nannote = {Cited By (since 1996): 20\n\n \nExport Date: 15 January 2013\n\n \nSource: Scopus\n\n \nCODEN: CMATE\n\n \ndoi: 10.1021/cm050976g\n\n \nLanguage of Original Document: English\n\n \nCorrespondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 C\\'{a}diz, Spain; email: jose.calvino@uca.es\n\n \nReferences: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10; \nIzu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107; \nBaker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodr\\'{\\i}guez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149; \nFornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Mart\\'{\\i}nez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149; \nMontini, T., Ba\\~{n}ares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1; \nMontini, T., Hickey, N., Fornasiero, P., Graziani, M., Ba\\~{n}ares, M.A., Mart\\'{\\i}nez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157; \nKishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. 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