Solid-State Structures of (R3P)2PtX2 Complexes As Determined by a Combination of 3C\1H\ and 31P\1H\ NMR Spectroscopy. Rahn, J. A., Nelson, J. H., & Baltusis, L. Inorganic Chemistry, 29(4):750–755, 1990. doi abstract bibtex Cross-polarization, combined with magic-angle spinning, has been employed to obtain high-resolution solid-state 13C and 31P NMR spectra of a series of 31 (R3P)2PtX2 complexes. These data together with spectra obtained in solution were used to compare the solid-state structures with those in solution. It was found that most of these complexes, which have regular square-planar structures in solution, are distorted in the solid state. The extent of the solid-state distortion is a function of the bulk of the coordinated ligands and increases as the ligand size increases. The solid-state distortions appear to result from intramolecular steric effects for cis-(R3P)2PtX2 and probably from intermolecular crystal packing forces for trans-(R3P)2PtX2. © 1990, American Chemical Society. All rights reserved.
@article{rahn_solid-state_1990,
title = {Solid-{State} {Structures} of ({R3P}){2PtX2} {Complexes} {As} {Determined} by a {Combination} of {3C}\{{1H}\} and {31P}\{{1H}\} {NMR} {Spectroscopy}},
volume = {29},
issn = {1520510X},
doi = {10.1021/ic00329a036},
abstract = {Cross-polarization, combined with magic-angle spinning, has been employed to obtain high-resolution solid-state 13C and 31P NMR spectra of a series of 31 (R3P)2PtX2 complexes. These data together with spectra obtained in solution were used to compare the solid-state structures with those in solution. It was found that most of these complexes, which have regular square-planar structures in solution, are distorted in the solid state. The extent of the solid-state distortion is a function of the bulk of the coordinated ligands and increases as the ligand size increases. The solid-state distortions appear to result from intramolecular steric effects for cis-(R3P)2PtX2 and probably from intermolecular crystal packing forces for trans-(R3P)2PtX2. © 1990, American Chemical Society. All rights reserved.},
number = {4},
journal = {Inorganic Chemistry},
author = {Rahn, Jeffrey A. and Nelson, John H. and Baltusis, Laima},
year = {1990},
pages = {750--755},
}
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