@article{
 title = {The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene},
 type = {article},
 year = {2002},
 identifiers = {[object Object]},
 keywords = {Gas-phase reaction,alkoxy radicals,atmospheric reactions,decomposition,kinetics,mechanism,nox,photooxidation,rate constants,temperature},
 pages = {255-261},
 volume = {34},
 id = {29010179-d2ba-357e-a4c9-e6efae913352},
 created = {2015-05-08T02:31:36.000Z},
 file_attached = {true},
 profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},
 group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
 last_modified = {2015-05-08T12:55:29.000Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 source_type = {Journal Article},
 notes = {<b>From Duplicate 1 (<i>The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene</i> - Reitz, J E; McGivern, W S; Church, M C; Wilson, M D; North, S W)<br/></b><br/>Article},
 abstract = {Rate constants for several intermediate steps in the OH- initiated oxidation of isoprene were determined using laser- photolysis/laser-induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K, The rate constant for decomposition of the hydroxyalkoxy radical was determined to be (3.0 +/- 0.5) x 10(4) s(-1) in this pressure range, which is in fair agreement with previous work. The presence of a prompt alkoxy decomposition pathway was also investigated and found to contribute less than 10% to the total hydroxyalkoxy radical decomposition. The rate constant for the reaction of the hydroxyperoxy radical with NO was determined to be (2.5 +/- 0.5) x 10(-11) cm(3) molecule(-1) s(-1), which is moderately higher than previously reported. (C) 2002 Wiley Periodicals, Inc.},
 bibtype = {article},
 author = {Reitz, June E and Sean McGivern, W. and Clark Church, M. and Wilson, Marc D and North, Simon W and McGivern, W S and Church, M C and Wilson, Marc D and North, Simon W},
 journal = {International Journal of Chemical Kinetics},
 number = {4}
}

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The presence of a prompt alkoxy decomposition pathway was also investigated and found to contribute less than 10% to the total hydroxyalkoxy radical decomposition. The rate constant for the reaction of the hydroxyperoxy radical with NO was determined to be (2.5 +/- 0.5) x 10(-11) cm(3) molecule(-1) s(-1), which is moderately higher than previously reported. 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