The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene. Reitz, J., E., Sean McGivern, W., Clark Church, M., Wilson, M., D., North, S., W., McGivern, W., S., Church, M., C., Wilson, M., D., & North, S., W. International Journal of Chemical Kinetics, 34(4):255-261, 2002.
Paper abstract bibtex Rate constants for several intermediate steps in the OH- initiated oxidation of isoprene were determined using laser- photolysis/laser-induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K, The rate constant for decomposition of the hydroxyalkoxy radical was determined to be (3.0 +/- 0.5) x 10(4) s(-1) in this pressure range, which is in fair agreement with previous work. The presence of a prompt alkoxy decomposition pathway was also investigated and found to contribute less than 10% to the total hydroxyalkoxy radical decomposition. The rate constant for the reaction of the hydroxyperoxy radical with NO was determined to be (2.5 +/- 0.5) x 10(-11) cm(3) molecule(-1) s(-1), which is moderately higher than previously reported. (C) 2002 Wiley Periodicals, Inc.
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title = {The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene},
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notes = {<b>From Duplicate 1 (<i>The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene</i> - Reitz, J E; McGivern, W S; Church, M C; Wilson, M D; North, S W)<br/></b><br/>Article},
abstract = {Rate constants for several intermediate steps in the OH- initiated oxidation of isoprene were determined using laser- photolysis/laser-induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K, The rate constant for decomposition of the hydroxyalkoxy radical was determined to be (3.0 +/- 0.5) x 10(4) s(-1) in this pressure range, which is in fair agreement with previous work. The presence of a prompt alkoxy decomposition pathway was also investigated and found to contribute less than 10% to the total hydroxyalkoxy radical decomposition. The rate constant for the reaction of the hydroxyperoxy radical with NO was determined to be (2.5 +/- 0.5) x 10(-11) cm(3) molecule(-1) s(-1), which is moderately higher than previously reported. (C) 2002 Wiley Periodicals, Inc.},
bibtype = {article},
author = {Reitz, June E and Sean McGivern, W. and Clark Church, M. and Wilson, Marc D and North, Simon W and McGivern, W S and Church, M C and Wilson, Marc D and North, Simon W},
journal = {International Journal of Chemical Kinetics},
number = {4}
}
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