Production of synthesis gas by partial oxidation and steam reforming of biomass pyrolysis oils. Rennard, D., French, R., Czernik, S., Josephson, T., & Schmidt, L. International Journal of Hydrogen Energy, 35(9):4048-4059, 2010.
Production of synthesis gas by partial oxidation and steam reforming of biomass pyrolysis oils [link]Website  abstract   bibtex   
As the lowest cost biomass-derived liquids, pyrolysis oils (also called bio-oils) represent a promising vector for biomass to fuels conversion. However, bio-oils require upgrading to interface with existing infrastructure. A potential pathway for producing fuels from pyrolysis oils proceeds through gasification, the conversion to synthesis gas. In this work, the conversion of bio-oils to syngas via catalytic partial oxidation over Rh-Ce is evaluated using two reactor configurations. In one instance, pyrolysis oils are oxidized in excess steam in a freeboard and passed over the catalyst in a second zone. In the second instance, bio-oils are introduced directly to the catalyst. Coke formation is avoided in both configurations due to rapid oxidation. H2 and CO can be produced autothermally over Rh-Ce catalysts with millisecond contact times. Co-processing of bio-oil with methane or methanol improved the reactor operation stability. ?? 2010 Professor T. Nejat Veziroglu.
@article{
 title = {Production of synthesis gas by partial oxidation and steam reforming of biomass pyrolysis oils},
 type = {article},
 year = {2010},
 identifiers = {[object Object]},
 keywords = {Bio-oil,Catalytic partial oxidation,Pyrolysis oil,Rhodium,Steam reforming,Syngas},
 pages = {4048-4059},
 volume = {35},
 websites = {http://doi.org/10.1016/j.ijhydene.2010.01.143},
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 abstract = {As the lowest cost biomass-derived liquids, pyrolysis oils (also called bio-oils) represent a promising vector for biomass to fuels conversion. However, bio-oils require upgrading to interface with existing infrastructure. A potential pathway for producing fuels from pyrolysis oils proceeds through gasification, the conversion to synthesis gas. In this work, the conversion of bio-oils to syngas via catalytic partial oxidation over Rh-Ce is evaluated using two reactor configurations. In one instance, pyrolysis oils are oxidized in excess steam in a freeboard and passed over the catalyst in a second zone. In the second instance, bio-oils are introduced directly to the catalyst. Coke formation is avoided in both configurations due to rapid oxidation. H2 and CO can be produced autothermally over Rh-Ce catalysts with millisecond contact times. Co-processing of bio-oil with methane or methanol improved the reactor operation stability. ?? 2010 Professor T. Nejat Veziroglu.},
 bibtype = {article},
 author = {Rennard, David and French, Rick and Czernik, Stefan and Josephson, Tyler and Schmidt, Lanny},
 journal = {International Journal of Hydrogen Energy},
 number = {9}
}

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