Direct conversion of cellulose to sorbitol over ruthenium catalysts: Influence of the support. Ribeiro, L., Delgado, J., de Melo Órfão, J., & Pereira, M. Catalysis Today, 279:244-251, 2017. cited By 24
Direct conversion of cellulose to sorbitol over ruthenium catalysts: Influence of the support [link]Paper  doi  abstract   bibtex   
Ruthenium-based catalysts were prepared by incipient wetness impregnation of different supports and characterized by TPR, TEM, ICP and N2 adsorption at −196 °C. The catalytic performances of the catalysts were evaluated in the hydrolytic hydrogenation of cellulose. The prepared catalysts were highly efficient, allowing conversions of cellulose higher than 75% after 5 h of reaction. The highest selectivity to sorbitol (over 60%) was reached when using carbon nanotubes (CNT) as support. Moreover, if this catalyst was ball-milled together with cellulose, that selectivity to sorbitol could be achieved in only 1 h of reaction and with complete conversion of cellulose. © 2016 Elsevier B.V.
@ARTICLE{Ribeiro2017244,
author={Ribeiro, L.S. and Delgado, J.J. and de Melo Órfão, J.J. and Pereira, M.F.R.},
title={Direct conversion of cellulose to sorbitol over ruthenium catalysts: Influence of the support},
journal={Catalysis Today},
year={2017},
volume={279},
pages={244-251},
doi={10.1016/j.cattod.2016.05.028},
note={cited By 24},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84973866250&doi=10.1016%2fj.cattod.2016.05.028&partnerID=40&md5=f26b8ae2462242e66a27f71d368bcd1a},
abstract={Ruthenium-based catalysts were prepared by incipient wetness impregnation of different supports and characterized by TPR, TEM, ICP and N2 adsorption at −196 °C. The catalytic performances of the catalysts were evaluated in the hydrolytic hydrogenation of cellulose. The prepared catalysts were highly efficient, allowing conversions of cellulose higher than 75% after 5 h of reaction. The highest selectivity to sorbitol (over 60%) was reached when using carbon nanotubes (CNT) as support. Moreover, if this catalyst was ball-milled together with cellulose, that selectivity to sorbitol could be achieved in only 1 h of reaction and with complete conversion of cellulose. © 2016 Elsevier B.V.},
keywords={Alcohols;  Carbon;  Carbon nanotubes;  Catalyst selectivity;  Catalysts;  Hydrogenation;  Ruthenium;  Yarn, Ball-milled;  Catalytic performance;  Direct conversion;  Incipientwetness impregnation;  Ru catalysts;  Ruthenium based catalysts;  Ruthenium catalysts;  Sorbitol, Cellulose},
document_type={Article},
source={Scopus},
}

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