{"_id":"twRk3yL5WzpgNBez6","bibbaseid":"ribeiro-delgado-rfo-pereira-carbonsupportedrunibimetalliccatalystsfortheenhancedonepotconversionofcellulosetosorbitol-2017","authorIDs":[],"author_short":["Ribeiro, L.","Delgado, J.","Órfão, J.","Pereira, M."],"bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Ribeiro"],"firstnames":["L.S."],"suffixes":[]},{"propositions":[],"lastnames":["Delgado"],"firstnames":["J.J."],"suffixes":[]},{"propositions":[],"lastnames":["Órfão"],"firstnames":["J.J.M."],"suffixes":[]},{"propositions":[],"lastnames":["Pereira"],"firstnames":["M.F.R."],"suffixes":[]}],"title":"Carbon supported Ru-Ni bimetallic catalysts for the enhanced one-pot conversion of cellulose to sorbitol","journal":"Applied Catalysis B: Environmental","year":"2017","volume":"217","pages":"265-274","doi":"10.1016/j.apcatb.2017.04.078","note":"cited By 48","url":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020298267&doi=10.1016%2fj.apcatb.2017.04.078&partnerID=40&md5=6714f9d79c8137ce30e025b72e3dc4ac","abstract":"Ru and Ni mono- and bimetallic catalysts were prepared by impregnation of two different supports (activated carbon and carbon nanotubes) and were characterized by TPR, TEM and N2 adsorption at −196 °C. The prepared Ru mono- and bimetallic catalysts were highly efficient for the hydrolytic hydrogenation of cellulose to sorbitol. Regardless of the support used, when nickel was incorporated into the supported ruthenium catalyst a promoting effect was observed, with an increase in both conversion and selectivity to sorbitol, which was explained by the interaction between both metals. Yields of sorbitol around 50–60% were achieved after 5 h of reaction when using Ru-Ni/AC and Ru-Ni/CNT as catalysts. Moreover, a yield of sorbitol over 70% could be reached in just 1 h of reaction if the Ru-Ni catalysts were ball-milled together with cellulose. © 2017 Elsevier B.V.","keywords":"Activated carbon; Alcohols; Catalyst selectivity; Catalysts; Cellulose; Hydrogenation; Nickel; Yarn, Ball-milled; Bimetallic catalysts; Ni catalysts; One pot; Promoting effect; Ruthenium catalysts; Sorbitol, Catalyst supports, Carbon; Catalysts; Cellulose; Glucitol","document_type":"Article","source":"Scopus","bibtex":"@ARTICLE{Ribeiro2017265,\nauthor={Ribeiro, L.S. and Delgado, J.J. and Órfão, J.J.M. and Pereira, M.F.R.},\ntitle={Carbon supported Ru-Ni bimetallic catalysts for the enhanced one-pot conversion of cellulose to sorbitol},\njournal={Applied Catalysis B: Environmental},\nyear={2017},\nvolume={217},\npages={265-274},\ndoi={10.1016/j.apcatb.2017.04.078},\nnote={cited By 48},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020298267&doi=10.1016%2fj.apcatb.2017.04.078&partnerID=40&md5=6714f9d79c8137ce30e025b72e3dc4ac},\nabstract={Ru and Ni mono- and bimetallic catalysts were prepared by impregnation of two different supports (activated carbon and carbon nanotubes) and were characterized by TPR, TEM and N2 adsorption at −196 °C. The prepared Ru mono- and bimetallic catalysts were highly efficient for the hydrolytic hydrogenation of cellulose to sorbitol. Regardless of the support used, when nickel was incorporated into the supported ruthenium catalyst a promoting effect was observed, with an increase in both conversion and selectivity to sorbitol, which was explained by the interaction between both metals. Yields of sorbitol around 50–60% were achieved after 5 h of reaction when using Ru-Ni/AC and Ru-Ni/CNT as catalysts. Moreover, a yield of sorbitol over 70% could be reached in just 1 h of reaction if the Ru-Ni catalysts were ball-milled together with cellulose. © 2017 Elsevier B.V.},\nkeywords={Activated carbon; Alcohols; Catalyst selectivity; Catalysts; Cellulose; Hydrogenation; Nickel; Yarn, Ball-milled; Bimetallic catalysts; Ni catalysts; One pot; Promoting effect; Ruthenium catalysts; Sorbitol, Catalyst supports, Carbon; Catalysts; Cellulose; Glucitol},\ndocument_type={Article},\nsource={Scopus},\n}\n\n","author_short":["Ribeiro, L.","Delgado, J.","Órfão, J.","Pereira, M."],"key":"Ribeiro2017265","id":"Ribeiro2017265","bibbaseid":"ribeiro-delgado-rfo-pereira-carbonsupportedrunibimetalliccatalystsfortheenhancedonepotconversionofcellulosetosorbitol-2017","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-85020298267&doi=10.1016%2fj.apcatb.2017.04.078&partnerID=40&md5=6714f9d79c8137ce30e025b72e3dc4ac"},"keyword":["Activated carbon; Alcohols; Catalyst selectivity; Catalysts; Cellulose; Hydrogenation; Nickel; Yarn","Ball-milled; Bimetallic catalysts; Ni catalysts; One pot; Promoting effect; Ruthenium catalysts; Sorbitol","Catalyst supports","Carbon; Catalysts; Cellulose; Glucitol"],"downloads":0,"html":"","metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"http://www2.uca.es/dept/cmat_qinor/nanomat/people/Group_5_years.bib","creationDate":"2020-10-26T16:39:31.556Z","downloads":0,"keywords":["activated carbon; alcohols; catalyst selectivity; catalysts; cellulose; hydrogenation; nickel; yarn","ball-milled; bimetallic catalysts; ni catalysts; one pot; promoting effect; ruthenium catalysts; sorbitol","catalyst supports","carbon; catalysts; cellulose; glucitol"],"search_terms":["carbon","supported","bimetallic","catalysts","enhanced","one","pot","conversion","cellulose","sorbitol","ribeiro","delgado","órfão","pereira"],"title":"Carbon supported Ru-Ni bimetallic catalysts for the enhanced one-pot conversion of cellulose to sorbitol","year":2017,"dataSources":["pLaxbtGnTnBzs2x8w"]}