Propene hydroformylation by supported aqueous-phase Rh-NORBOS catalysts. Riisager, A., Eriksena, K., Hjortkjær, J., & Fehrmann, R. Journal of Molecular Catalysis A: Chemical, 193(1-2):259–272, 2003.
Propene hydroformylation by supported aqueous-phase Rh-NORBOS catalysts [link]Paper  doi  abstract   bibtex   
The gas-phase hydroformylation reaction of propene using supported aqueous-phase (SAP) Rh-NORBOS modified catalysts in a continuous flow reactor has been examined. SAP catalysts supported on six different support materials were made by wet impregnation using solutions of the precursor complex Rh(acac)(CO)2 and NORBOS ligand. Catalytic performance of silica gel-based catalysts was examined by altering catalyst composition and reaction conditions. Results were compared to analogous TPPTS catalysts and to catalysts supported on alternative support materials, e.g. silica glass, alumina and carbon. Based on these results the aqueous and the homogeneous nature of the SAP catalysts are discussed. © 2002 Elsevier Science B.V. All rights reserved.
@article{riisager_propene_2003,
	title = {Propene hydroformylation by supported aqueous-phase {Rh}-{NORBOS} catalysts},
	volume = {193},
	url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-0037450222&doi=10.1016%2fS1381-1169%2802%2900471-5&partnerID=40&md5=9a181edf14ec950d13996d69109856ab},
	doi = {10.1016/S1381-1169(02)00471-5},
	abstract = {The gas-phase hydroformylation reaction of propene using supported aqueous-phase (SAP) Rh-NORBOS modified catalysts in a continuous flow reactor has been examined. SAP catalysts supported on six different support materials were made by wet impregnation using solutions of the precursor complex Rh(acac)(CO)2 and NORBOS ligand. Catalytic performance of silica gel-based catalysts was examined by altering catalyst composition and reaction conditions. Results were compared to analogous TPPTS catalysts and to catalysts supported on alternative support materials, e.g. silica glass, alumina and carbon. Based on these results the aqueous and the homogeneous nature of the SAP catalysts are discussed. © 2002 Elsevier Science B.V. All rights reserved.},
	number = {1-2},
	journal = {Journal of Molecular Catalysis A: Chemical},
	author = {Riisager, A. and Eriksena, K.M. and Hjortkjær, J. and Fehrmann, R.},
	year = {2003},
	keywords = {3,4 dimethyl 2,5,6 tris(4 sulfonatophenyl) 1 phosphanorbornadiene, Catalysts, Impregnation, Ligands, Propylene, Silica, Solutions, aluminum oxide, aqueous solution, article, carbon, catalysis, catalyst, chemical composition, chemical modification, chemical reaction, continuous flow reactor, gas analysis, glass, hydroformylation, ligand binding, materials testing, norbornadiene derivative, phase transition, propylene, rhodium, silicon dioxide, supported aqueous phase catalysis, unclassified drug, wet impregnation},
	pages = {259--272}
}

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