Application of random walk model to the glass transition of unsaturated polyester resins cured with different styrene contents. Saiter, A., Bureau, E., Zapolsky, H., Marais, S., & Saiter, J. M. Journal of Non-Crystalline Solids, 307–310:738–743, September, 2002. Paper doi abstract bibtex Dielectric measurements have been performed on unsaturated polyester resins, cured with different styrene contents. Based on the random walk model (RWM), we have determined, as a function of the styrene content, the width of the density of states kT0, the average energy barrier height 〈EA〉 that a structural unit must crossover in order to relax, the fragility index α and the value of Tc at which qualitative changes in the dynamics occur. The RWM data are in good agreement with the strong-fragile concept.
@article{saiter_application_2002,
title = {Application of random walk model to the glass transition of unsaturated polyester resins cured with different styrene contents},
volume = {307–310},
issn = {0022-3093},
url = {http://www.sciencedirect.com/science/article/pii/S0022309302015557},
doi = {10.1016/S0022-3093(02)01555-7},
abstract = {Dielectric measurements have been performed on unsaturated polyester resins, cured with different styrene contents. Based on the random walk model (RWM), we have determined, as a function of the styrene content, the width of the density of states kT0, the average energy barrier height 〈EA〉 that a structural unit must crossover in order to relax, the fragility index α and the value of Tc at which qualitative changes in the dynamics occur. The RWM data are in good agreement with the strong-fragile concept.},
urldate = {2014-12-18TZ},
journal = {Journal of Non-Crystalline Solids},
author = {Saiter, A. and Bureau, E. and Zapolsky, H. and Marais, S. and Saiter, J. M.},
month = sep,
year = {2002},
pages = {738--743}
}
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