Stabilized gold on cerium-modified cryptomelane: Highly active in low-temperature CO oxidation. Santos, V., Carabineiro, S., Bakker, J., Soares, O., Chen, X., Pereira, M., Orfao, J., Figueiredo, J., Gascon, J., & Kapteijn, F. Journal of Catalysis, 309:58--65, 2014.
Paper doi abstract bibtex Cerium-doped cryptomelane stabilizes polyhedron Au nano-particles smaller than 3 nm. The obtained Au/Ce/cryptomelane catalyst is highly active for CO oxidation. Cationic, neutral, and anionic gold species were found on Ce/cryptomelane. The modification of cryptomelane by the addition of cerium is twofold: (i) cerium is incorporated in the tunnels of cryptomelane, increasing the number of defects which function as nucleation sites for gold and (ii) ceria nano-particles at the surface induce charge transfer between gold and cryptomelane. TOF for Au/Ce-K-OMS-2 is about twice that of Au/CeO2 prepared by the same procedure. © 2013 Elsevier Inc. All rights reserved.
@article{ Santos201458,
abstract = {Cerium-doped cryptomelane stabilizes polyhedron Au nano-particles smaller than 3 nm. The obtained Au/Ce/cryptomelane catalyst is highly active for CO oxidation. Cationic, neutral, and anionic gold species were found on Ce/cryptomelane. The modification of cryptomelane by the addition of cerium is twofold: (i) cerium is incorporated in the tunnels of cryptomelane, increasing the number of defects which function as nucleation sites for gold and (ii) ceria nano-particles at the surface induce charge transfer between gold and cryptomelane. TOF for Au/Ce-K-OMS-2 is about twice that of Au/CeO2 prepared by the same procedure. © 2013 Elsevier Inc. All rights reserved.},
annote = {cited By (since 1996)0},
author = {Santos, VP. and Carabineiro, SAC. and Bakker, JJW. and Soares, OSGP. and Chen, X. and Pereira, M.F.R. and Orfao, JJM. and Figueiredo, JL. and Gascon, J. and Kapteijn, F.},
doi = {10.1016/j.jcat.2013.08.030},
issn = {00219517},
journal = {Journal of Catalysis},
keywords = {Au-nanoparticles,Cerium,Cerium doping,Cerium-doped,Co,Gold,Nanoparticles,Oxidation,Oxygen vacancies},
pages = {58--65},
title = {{Stabilized gold on cerium-modified cryptomelane: Highly active in low-temperature CO oxidation}},
url = {http://www.scopus.com/inward/record.url?eid=2-s2.0-84884965189&partnerID=40&md5=aec788dde77a763fe9cb3a1e9b3b96ba},
volume = {309},
year = {2014}
}
Downloads: 0
{"_id":{"_str":"53a0161a2d7be89727001e84"},"__v":1,"authorIDs":["545761e42abc8e9f37000341"],"author_short":["Santos, V.","Carabineiro, S.","Bakker, J.","Soares, O.","Chen, X.","Pereira, M.","Orfao, J.","Figueiredo, J.","Gascon, J.","Kapteijn, F."],"bibbaseid":"santos-carabineiro-bakker-soares-chen-pereira-orfao-figueiredo-gascon-kapteijn-stabilizedgoldonceriummodifiedcryptomelanehighlyactiveinlowtemperaturecooxidation-2014","bibdata":{"abstract":"Cerium-doped cryptomelane stabilizes polyhedron Au nano-particles smaller than 3 nm. The obtained Au/Ce/cryptomelane catalyst is highly active for CO oxidation. Cationic, neutral, and anionic gold species were found on Ce/cryptomelane. The modification of cryptomelane by the addition of cerium is twofold: (i) cerium is incorporated in the tunnels of cryptomelane, increasing the number of defects which function as nucleation sites for gold and (ii) ceria nano-particles at the surface induce charge transfer between gold and cryptomelane. TOF for Au/Ce-K-OMS-2 is about twice that of Au/CeO2 prepared by the same procedure. © 2013 Elsevier Inc. All rights reserved.","annote":"cited By (since 1996)0","author":["Santos, VP.","Carabineiro, SAC.","Bakker, JJW.","Soares, OSGP.","Chen, X.","Pereira, M.F.R.","Orfao, JJM.","Figueiredo, JL.","Gascon, J.","Kapteijn, F."],"author_short":["Santos, V.","Carabineiro, S.","Bakker, J.","Soares, O.","Chen, X.","Pereira, M.","Orfao, J.","Figueiredo, J.","Gascon, J.","Kapteijn, F."],"bibtex":"@article{ Santos201458,\n abstract = {Cerium-doped cryptomelane stabilizes polyhedron Au nano-particles smaller than 3 nm. The obtained Au/Ce/cryptomelane catalyst is highly active for CO oxidation. Cationic, neutral, and anionic gold species were found on Ce/cryptomelane. The modification of cryptomelane by the addition of cerium is twofold: (i) cerium is incorporated in the tunnels of cryptomelane, increasing the number of defects which function as nucleation sites for gold and (ii) ceria nano-particles at the surface induce charge transfer between gold and cryptomelane. TOF for Au/Ce-K-OMS-2 is about twice that of Au/CeO2 prepared by the same procedure. © 2013 Elsevier Inc. All rights reserved.},\n annote = {cited By (since 1996)0},\n author = {Santos, VP. and Carabineiro, SAC. and Bakker, JJW. and Soares, OSGP. and Chen, X. and Pereira, M.F.R. and Orfao, JJM. and Figueiredo, JL. and Gascon, J. and Kapteijn, F.},\n doi = {10.1016/j.jcat.2013.08.030},\n issn = {00219517},\n journal = {Journal of Catalysis},\n keywords = {Au-nanoparticles,Cerium,Cerium doping,Cerium-doped,Co,Gold,Nanoparticles,Oxidation,Oxygen vacancies},\n pages = {58--65},\n title = {{Stabilized gold on cerium-modified cryptomelane: Highly active in low-temperature CO oxidation}},\n url = {http://www.scopus.com/inward/record.url?eid=2-s2.0-84884965189&partnerID=40&md5=aec788dde77a763fe9cb3a1e9b3b96ba},\n volume = {309},\n year = {2014}\n}","bibtype":"article","doi":"10.1016/j.jcat.2013.08.030","id":"Santos201458","issn":"00219517","journal":"Journal of Catalysis","key":"Santos201458","keywords":"Au-nanoparticles,Cerium,Cerium doping,Cerium-doped,Co,Gold,Nanoparticles,Oxidation,Oxygen vacancies","pages":"58--65","title":"Stabilized gold on cerium-modified cryptomelane: Highly active in low-temperature CO oxidation","type":"article","url":"http://www.scopus.com/inward/record.url?eid=2-s2.0-84884965189&partnerID=40&md5=aec788dde77a763fe9cb3a1e9b3b96ba","volume":"309","year":"2014","bibbaseid":"santos-carabineiro-bakker-soares-chen-pereira-orfao-figueiredo-gascon-kapteijn-stabilizedgoldonceriummodifiedcryptomelanehighlyactiveinlowtemperaturecooxidation-2014","role":"author","urls":{"Paper":"http://www.scopus.com/inward/record.url?eid=2-s2.0-84884965189&partnerID=40&md5=aec788dde77a763fe9cb3a1e9b3b96ba"},"keyword":["Au-nanoparticles","Cerium","Cerium doping","Cerium-doped","Co","Gold","Nanoparticles","Oxidation","Oxygen vacancies"],"downloads":0,"html":""},"bibtype":"article","biburl":"http://www2.uca.es/dept/cmat_qinor/nanomat/people/Chen.bib","downloads":0,"keywords":["au-nanoparticles","cerium","cerium doping","cerium-doped","co","gold","nanoparticles","oxidation","oxygen vacancies"],"search_terms":["stabilized","gold","cerium","modified","cryptomelane","highly","active","low","temperature","oxidation","santos","carabineiro","bakker","soares","chen","pereira","orfao","figueiredo","gascon","kapteijn"],"title":"Stabilized gold on cerium-modified cryptomelane: Highly active in low-temperature CO oxidation","year":2014,"dataSources":["3vwztvA25ozghRWcr"]}