Synthesis of poly(vinyl alcohol) having a thiol group at one end and new block copolymers containing poly(vinyl alchohol) as one constitent. Sato, T., Terada, K., Yamauchi, J., & Okaya, T. Die Makromolekulare Chemie, 194(1):175–185, 1993. _eprint: https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1993.021940114
Synthesis of poly(vinyl alcohol) having a thiol group at one end and new block copolymers containing poly(vinyl alchohol) as one constitent [link]Paper  doi  abstract   bibtex   
Poly(vinyl alcohol) (PVA) and poly(vinyl acetate) having a thiol group at one end were synthesized by free-radical polymerization of vinyl acetate in presence of thioacetic acid as a chain transfer agent followed by treating with sodium hydroxide/methanol and ammonia, respectively. It was found that block copolymers containing the PVA sequence as one constituent were obtained by the redox-initiated polymerization of some vinyl monomers, for example, acrylic acid (AA) and acrylamide (AAm), using PVA having a thiol end group as reductant and an oxidant such as potassium bromate and potassium persulfate.
@article{sato_synthesis_1993,
	title = {Synthesis of poly(vinyl alcohol) having a thiol group at one end and new block copolymers containing poly(vinyl alchohol) as one constitent},
	volume = {194},
	issn = {0025-116X},
	url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.1993.021940114},
	doi = {10.1002/macp.1993.021940114},
	abstract = {Poly(vinyl alcohol) (PVA) and poly(vinyl acetate) having a thiol group at one end were synthesized by free-radical polymerization of vinyl acetate in presence of thioacetic acid as a chain transfer agent followed by treating with sodium hydroxide/methanol and ammonia, respectively. It was found that block copolymers containing the PVA sequence as one constituent were obtained by the redox-initiated polymerization of some vinyl monomers, for example, acrylic acid (AA) and acrylamide (AAm), using PVA having a thiol end group as reductant and an oxidant such as potassium bromate and potassium persulfate.},
	language = {en},
	number = {1},
	urldate = {2021-11-01},
	journal = {Die Makromolekulare Chemie},
	author = {Sato, Toshiaki and Terada, Kazutoshi and Yamauchi, Junnosuke and Okaya, Takuji},
	year = {1993},
	note = {\_eprint: https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1993.021940114},
	pages = {175--185},
}

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