Stochastic temperature modulation: A new technique in temperature-modulated DSC. Schawe, J.&nbsp;E.<nbsp>K., Hütter, T., Heitz, C., Alig, I., & Lellinger, D. Thermochimica Acta, 446(1–2):147--155, 2006.
Stochastic temperature modulation: A new technique in temperature-modulated DSC [link]Paper  doi  abstract   bibtex   
A new temperature-modulated differential scanning calorimetry (TMDSC) technique is introduced. The technique is based on stochastic temperature modulation and has been developed as a consequence of a generalized theory of a temperature-modulated DSC. The quasi-static heat capacity and the frequency-dependent complex heat capacity can be determined over a wide frequency range in one single measurement without further calibration. Furthermore, the reversing and non-reversing heat flows are determined directly from the measured data. Examples show the frequency dependence of the glass transition, the isothermal curing of thermosets and a solid–solid transition.
@article{ schawe_stochastic_2006,
  series = {Honour Issue on the Retirement of Prof. W. Hemminger},
  title = {Stochastic temperature modulation: A new technique in temperature-modulated {DSC}},
  volume = {446},
  issn = {0040-6031},
  shorttitle = {Stochastic temperature modulation},
  url = {http://www.sciencedirect.com/science/article/pii/S0040603106000736},
  doi = {10.1016/j.tca.2006.01.031},
  abstract = {A new temperature-modulated differential scanning calorimetry ({TMDSC}) technique is introduced. The technique is based on stochastic temperature modulation and has been developed as a consequence of a generalized theory of a temperature-modulated {DSC}. The quasi-static heat capacity and the frequency-dependent complex heat capacity can be determined over a wide frequency range in one single measurement without further calibration. Furthermore, the reversing and non-reversing heat flows are determined directly from the measured data. Examples show the frequency dependence of the glass transition, the isothermal curing of thermosets and a solid–solid transition.},
  number = {1–2},
  urldate = {2014-09-11TZ},
  journal = {Thermochimica Acta},
  author = {Schawe, J. E. K. and Hütter, T. and Heitz, C. and Alig, I. and Lellinger, D.},
  year = {2006},
  keywords = {Heat capacity, Stochastic temperature modulation, {TOPEM}®, Temperature-modulated {DSC}},
  pages = {147--155}
}
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