Structural and reactivity insights into covalently linked Cu(i) complex-Anderson polyoxometalates. Schönweiz, S., Sorsche, D., Schwarz, B., Rau, S., & Streb, C. Dalton Transactions, 2017.
abstract   bibtex   
© 2017 The Royal Society of Chemistry. The synthesis, crystallographic analysis and full characterization of the Cu(i) complex-functionalized Anderson polyoxomolybdate anions ( n Bu 4 N)[MMo 6 O 18 ((OCH 2 ) 3 CNCH(C 47 H 37 N 2 P 2 OCu) 2 )] (M = Mn 3+ , Fe 3+ , Co 3+ ) is reported. For the first time, direct crystallographic evidence for the covalent attachment of a photoactive metal complex to an organo-functionalized polyoxometalate is obtained. Initial electrochemical and photochemical studies report fundamental properties and solution stability of the compounds.
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 title = {Structural and reactivity insights into covalently linked Cu(i) complex-Anderson polyoxometalates},
 type = {article},
 year = {2017},
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 abstract = {© 2017 The Royal Society of Chemistry. The synthesis, crystallographic analysis and full characterization of the Cu(i) complex-functionalized Anderson polyoxomolybdate anions ( n Bu 4 N)[MMo 6 O 18 ((OCH 2 ) 3 CNCH(C 47 H 37 N 2 P 2 OCu) 2 )] (M = Mn 3+ , Fe 3+ , Co 3+ ) is reported. For the first time, direct crystallographic evidence for the covalent attachment of a photoactive metal complex to an organo-functionalized polyoxometalate is obtained. Initial electrochemical and photochemical studies report fundamental properties and solution stability of the compounds.},
 bibtype = {article},
 author = {Schönweiz, S. and Sorsche, D. and Schwarz, B. and Rau, S. and Streb, C.},
 journal = {Dalton Transactions},
 number = {30}
}

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