@ARTICLE{Shahat2017164,
author={Shahat, A. and Elsalam, S.A. and Herrero-Martínez, J.M. and Simó-Alfonso, E.F. and Ramis-Ramos, G.},
title={Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF},
journal={Sensors and Actuators, B: Chemical},
year={2017},
volume={253},
pages={164-172},
doi={10.1016/j.snb.2017.06.125},
note={cited By 54},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021052709&doi=10.1016%2fj.snb.2017.06.125&partnerID=40&md5=de941ee53eb0fe07777429b91e6852d5},
affiliation={Department of Chemistry, Faculty of Science, Suez University, Suez, Egypt; Department of Analytical Chemistry, University of Valencia, C. Doctor Moliner 50, E-46100 Burjassot, Valencia, Spain},
abstract={We developed a simple self-chemical optical sensor for the monitoring and removal of ultra-trace levels of Hg(II) from aqueous media. The development of this sensor was based on the covalent attachment of amino-functionalized aluminum-based MOF particles with ninhydrin. The new sensor is densely coated with a chelating ligand to permit an ultra-fast, selective, pH-dependent visualization for removal of Hg(II) with detection limit (LOD∼0.494 μg L−1). Monitoring was accomplished via both a colorimetric signal visible to the naked eye as well as UV–vis absorption spectroscopy. Digital image-based colorimetric analysis has also used as a semi-quantitative analysis for determination the concentration of Hg(II) ions as a fast, sensitive and low-cost colorimetric detection system. Further, the new robust sensor exhibited long-term stability and high reusability. The developed sensor was also successfully applied to the determination and removal of Hg(II) from silver oxide button cells. © 2017 Elsevier B.V.},
author_keywords={Colorimetric;  Electronic wastes;  Mercury;  MOF;  Self-chemosensor},
keywords={Absorption spectroscopy;  Color;  Colorimetric analysis;  Colorimetry;  Electronic Waste;  Java programming language;  Physiology;  Reusability, Chemosensor;  Colorimetric;  Colorimetric detection;  Covalent attachment;  Determination and removals;  Long term stability;  Semi-quantitative analysis;  VIS absorption spectroscopy, Mercury (metal)},
references={Basu, N., Kwan, M., Chan, H.M., Mercury but not organochlorines inhibits muscarinic cholinergic receptor binding in the cerebrum of ringed seals (Phoca hispida) (2006) J. Toxicol. Environ. Health, A, 69, pp. 1133-1143; Bessbousse, H., Rhlalou, T., Verchere, J.-F., Lebrun, L.L., Removal of heavy metal ions from aqueous solutions by filtration with a novel complexing membrane containing poly (ethyleneimine) in a poly (vinyl alcohol) matrix (2008) J. Membr. Sci., 307, pp. 249-259; El-Safty, S.A., Ismail, A., Matsunaga, T., Mizukami, F., Optical nanosensor design with uniform pore geometry and large particle morphology (2007) Chem. Eur. J., 13, p. 9245; Renzoni, A., Zino, F., Franchi, E., Mercury levels along the food chain and risk for exposed populations (1998) Environ. Res., 77, pp. 68-72; Ros-Lis, J.V., Marcos, M.D., Martinez-Manez, R., Rurack, K., Soto, J., A regenerative chemodosimeter based on metal induced dye formation for the highly selective and sensitive optical determination of Hg2+ ions (2005) Angew. Chem. Int. Ed., 44, pp. 4405-4407; US EPA, Edition of the Drinking Water Standards and Health Advisories (2012), US Environmental Protection Agency Washington, DC (April, 2012, EPA 822-S-12- 001); Letelier, M.E., Lepe, A.M., Faundez, M., Salazar, J., Marin, R., Aracena, P., Speisky, H., Possible mechanisms underlying copper-induced damage in biological membranes leading to cellular toxicity (2005) Chem. Chem.-Biol. Interact., 151, pp. 71-82; Wei, Y., Gao, C., Meng, F.L., Li, H.H., Wang, L., Liu, J.H., Huang, X.J., SnO2/reduced graphene oxide nanocomposite for the simultaneous electrochemical detection of cadmium(II), lead(II), copper(II), and mercury(II): an interesting favorable mutual interference (2012) Phys. Chem. C, 116, pp. 1034-1041; Chen, J., Chen, H., Jin, X., Chen, H., Determination of ultra-trace amount methyl-, phenyl- and inorganic mercury in environmental and biological samples by liquid chromatography with inductively coupled plasma mass spectrometry after cloud point extraction preconcentration (2009) Talanta, 77, pp. 1381-1387; de Wuilloud, J.C.A., Wuilloud, R.G., Silva, M.F., Olsina, R.A., Martinez, L.D., Sensitive determination of mercury in tap water by cloud point extraction pre-concentration and flow injection-cold vapor-inductively coupled plasma optical emission spectrometry (2002) Spectrochim. Acta, B, 57, pp. 365-374; Shahat, A., Ali, E.A., El Shahat, M.F., Colorimetric determination of some toxic metal ions in post-mortembiological samples (2015) Sens. Actuators, B, 221, pp. 1027-1034; Shahat, A., Awual, M.R., Khaleque, M.A., Alam, M.Z., Naushad, M., Chowdhury, A.M.S., Large-pore diameter nano-adsorbent and its application for rapid lead(II) detection and removal from aqueous media (2015) Chem. Eng. J., 273, pp. 286-295; Rabiul Awual, M., Shadhin, M.H., Shahat, A., Functionalized novel mesoporous adsorbent for selective Lead(II) ions monitoring and removal from wastewater (2014) Sens. Actuators B, 203, p. 854; El-Safty, S.A., Shenashen, M.A., Shahat, A., Tailor-made micro-object optical sensor based on mesoporous pellets for visual monitoring and removal of toxic metal ions from aqueous media (2013) Small, 9, pp. 2288-2292; Shahat, A., Hassan, H.M.A., Azzazy, H.M.E., Optical metal-organic framework sensor for selective discrimination of some toxic metal ions in water (2013) Anal. Chim. Acta, 793, pp. 90-98; Shenashena, M.A., Shahat, A., El-Safty, S.A., Ultra-trace recognition and removal of toxic chromium (VI) ions from water using visual mesocaptor (2013) J. Haz. Mat., 244, pp. 726-735; El-Safty, S.A., Abdellatef, S., Ismael, M., Shahat, A., Optical nanosphere sensor based on shell-By-Shell fabrication for removal of toxic metals from human blood (2013) Adv. Healthcare Mater., 2, pp. 854-862; Lu, Q., Gao, F., Komarneni, S., Mallouk, T.E., Ordered SBA-15 nanorod arrays inside a porous alumina membrane (2005) J. Am. Chem. Soc., 126, pp. 8650-8651; Ferey, G., Hybrid porous solids: past, present, future (2008) Chem. Soc. Rev., 37, pp. 191-214; Tranchemontagne, D.J., Mendoza-Cortés, J.L., O'Keeffea, M., Yaghi, O.M., Secondary building units, nets and bonding in the chemistry of metal–organic frameworks (2009) Chem. Soc. Rev., 38, pp. 1257-1283; Stock, N., Biswas, S., Synthesis of metal-Organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites (2012) Chem. Rev., 112, pp. 933-969; Li, J.R., Sculley, J., Zhou, H.C., Metal-organic frameworks for separations (2012) Chem. Rev., 112, pp. 869-932; Sumida, K., Rogow, D.L., Mason, J.A., McDonald, T.M., Bloch, E.D., Herm, Z.R., Bae, T.H., Long, J.R., Carbon dioxide capture in metal-organic frameworks (2012) Chem. Rev., 112, pp. 724-781; Serra-Crespo, P., Ramos-Fernandez, E.V., Gascon, J., Kapteijn, F., Synthesis and characterization of an amino functionalized MIL-101(Al): separation and catalytic properties (2011) Chem. Mater., 23, pp. 2565-2572; Bromberg, L., Klichko, Y., Chang, E.P., Speakman, S., Straut, C.M., Wilusz, E., Hatton, T.A., Alkylaminopyridine-modified aluminum aminoterephthalate metal- organic frameworks as components of reactive self-detoxifying materials (2012) Appl. Mater. Interfaces, 4, pp. 4595-4602; Bromberg, L., Su, X., Alan Hatton, T., Aldehyde self-condensation catalysis by aluminum aminoterephthalate metal-organic frameworks modified with aluminum isopropoxide (2013) Chem. Mater., 25, pp. 1636-1642; Hartmann, M., Fischer, M., Amino-functionalized basic catalysts with MIL-101 structure (2012) Microp. Mesop. Materials, 164, pp. 38-43; Toyao, T., Fujiwaki, M., Horiuchi, Y., Matsuoka, M., Application of an amino-functionalised metal–organic framework: an approach to a one-pot acid–base reaction (2013) RSC Adv., 3, pp. 21582-21587; Haque, E., Lo, V., Minett, A.I., Harris, A.T., Church, T.L., Dichotomous adsorption behaviour of dyes on an amino-functionalised metal–organic framework, amino-MIL-101(Al) (2014) J. Mater. Chem., 2, pp. 193-203. , (A); Cheng, X., Zhang, A., Hou, K., Liu, M., Wang, Y., Song, C., Zhange, G., Guo, X., Size- and morphology-controlled NH2-MIL-53(Al) prepared in DMF–water mixed solvents (2013) Dalton Trans., 42, pp. 13698-13705; Friedman, M., The chemistry of ninhydrin (1967) Canad. J. Chem, 45, pp. 2271-2275; Llewellyn, P.L., Bourrelly, S., Serre, C., Vimont, A., Daturi, M., Hamon, L., De Weireld, G., Ferey, G., High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101 (2008) Langmuir, 24, pp. 7245-7250; Gascon, J., Aktay, U., Hernandez-Alonso, M.D., van Klink, G.P.M., Kapteijn, F., Amino-based metal-organic frameworks as stable, highly active basic catalysts (2009) J. Catal., 261, pp. 75-87; Huang, Y., Zheng, Z., Liu, T., Lü, J., Li, H., Cao, R., Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki–Miyaura cross-coupling reaction (2011) Catal. Commun., 14, pp. 27-31; Hong, D.Y., Hwang, Y.K., Serre, C., Ferey, G., Chang, J.S., Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis (2009) Adv. Funct. Mater., 19, pp. 1537-1552; Khalil, M.M.H., Shahat, A., Radwan, A., El-Shahat, M.F., Colorimetric determination of Cu (II) ions in biological samples using metal-organic framework as scaffold (2016) Sens. Actuators, B, 233, pp. 272-280; Awual, M.R., Hasan, M.M., Shahat, A., Naushad, M., Shiwaku, H., Yaita, T., Investigation of ligand immobilized nano-composite adsorbent for efficient cerium(III) detection and recovery (2015) Chem. Eng. J., 265, pp. 210-215; Christian, G.D., Analytical Chemistry (2003), 6th ed. Wiley New York; Hamza, A., Bashammakh, A.S., Al-Sibaai, A.A., Al-Saidi, H.M., El-Shahawi, M.S., Part 1. Spectrophotometric determination of trace mercury (II) in dental-unit wastewater and fertilizer samples using the novel reagent 6-hydroxy-3-(2-oxoindolin-3-ylideneamino)-2-thioxo-2H-1 3-thiazin-4(3H)-one and the dual-wavelength −correction spectrophotometry (2010) J. Hazard. Mater., 178, pp. 287-292; Jamaluddin Ahmed, M., Shah Alam, M., A rapid spectrophotometric method for the determination of mercury in environmental, biological, soil and plant samples using diphenylthiocarbazone (2003) Spectroscopy, 17, pp. 45-52; Jeoung, M.-S., Choi, H.-S., Spectrophotometric determination of trace Hg(II) in cetyltrimethylammonium bromide media (2004) Bull. Korean Chem. Soc., 25 (12), pp. 1877-1881; Nekoue, F., Nekoue, S., Spectrophotometric determination of mercury (II) by simultaneous micelle mediated extraction through ternary complex formation in water samples (2014) Orient. J. Chem., Vol., 30 (2), pp. 867-871; Loo, A.Y.Y., Lay, Y.P., Kutty, M.G., Timpe, O., Spectrophotometric determination of mercury with iodide and rhodamine B (2012) Sains Malaysiana, 41 (2), pp. 213-218; Deepa, K., Raj, Y.P., Lingappa, Y., Spectrophotometric determination of Mercury in environmental samples using 5-methylthiophene-2-carboxaldehyde ethylenediamine (MTCED) (2014) Der Pharma Chemica, 6 (3), pp. 48-55; Buszewski, B., Szultka, M., Past, present, and future of solid phase extraction: a review (2012) Crit. Rev. Anal. Chem., 42, pp. 198-213; Langmuir, I., The adsorption of gases on plane surfaces of glass, mica and platinum (1918) J. Chem. Am. Soc., 40, pp. 1361-1403; Shenashen, M.A., Elshehy, E.A., El-Safty, S.A., Khairy, M., Visual monitoring and removal of divalent copper, cadmium, and mercury ions from water by using mesoporous cubic Ia3d aluminosilica sensors (2013) Sep. Purif. Technol., 116, pp. 73-86; Girginova, P.I., da-Silva, A.L., Lopes, C.B., Figueira, P., Otero, M., Amaral, V.S., Pereira, E., Trindade, T., Silica coated magnetite particles for magnetic removal of Hg2+ from water (2010) J. Colloid Interface Sci., 345, pp. 234-240; El-Safty, S.A., Shenashen, M.A., Optical mesosensor for capturing of Fe(III) and Hg(II) ions from water and physiological fluids (2013) Sens. and Actu. B, 183, pp. 58-70; Tzvetkova, P., Nickolov, R., Modified and unmodified silica gel used for heavy metal ions removal from aqueous (2012) J. Univ. Chem. Technol. Metall., 47, pp. 498-504; Huang, C., Hu, B., Silica-coated magnetic nanoparticles modified with γ-mercaptopropyltrimethoxysilane for fast and selective solid phase extraction of trace amounts of Cd, Cu, Hg, and Pb in environmental and biological samples prior to their determination by inductively coupled plasma mass spectrometry (2008) Spectro. chim. Acta Part B, 63, pp. 437-444; Fuliu, J., Hanzhao, Z.S., Binjiang, A., Coating Fe3O4 magnetic nanoparticles with humic acid for high efficient removal of heavy metals in water (2008) Environ. Sci. Technol., 42, pp. 6949-6954; Kompany-Zareh, M., Mansourian, M., Ravaee, F., Simple method for colorimetric spot-test quantitative analysis of Fe(III) using a computer controlled hand-scanner (2002) Anal. Chim. Acta, 471, pp. 97-104; Aktas, S., Silver recovery from spent silver oxide button cells (2010) Hydrometallurgy, 104, pp. 106-111; Oh, C.J., Lee, S.O., Yang, H.S., Ha, T.J., Kim, M.J., Selective leaching of valuable metals from waste printed circuit boards (2003) J. Air Waste Manage., 53 (7), pp. 897-902},
correspondence_address1={Shahat, A.; Department of Chemistry, Egypt; email: ashahat@aucegypt.edu},
publisher={Elsevier B.V.},
issn={09254005},
coden={SABCE},
language={English},
abbrev_source_title={Sens Actuators, B Chem},
document_type={Article},
source={Scopus},
}

{"_id":"ihZ2Xn8Jo5XQoTfyJ","bibbaseid":"shahat-elsalam-herreromartnez-simalfonso-ramisramos-opticalrecognitionandremovalofhgiiusinganewselfchemosensorbasedonamodifiedaminofunctionalizedalmof-2017","author_short":["Shahat, A.","Elsalam, S.","Herrero-Martínez, J.","Simó-Alfonso, E.","Ramis-Ramos, G."],"bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Shahat"],"firstnames":["A."],"suffixes":[]},{"propositions":[],"lastnames":["Elsalam"],"firstnames":["S.A."],"suffixes":[]},{"propositions":[],"lastnames":["Herrero-Martínez"],"firstnames":["J.M."],"suffixes":[]},{"propositions":[],"lastnames":["Simó-Alfonso"],"firstnames":["E.F."],"suffixes":[]},{"propositions":[],"lastnames":["Ramis-Ramos"],"firstnames":["G."],"suffixes":[]}],"title":"Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF","journal":"Sensors and Actuators, B: Chemical","year":"2017","volume":"253","pages":"164-172","doi":"10.1016/j.snb.2017.06.125","note":"cited By 54","url":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021052709&doi=10.1016%2fj.snb.2017.06.125&partnerID=40&md5=de941ee53eb0fe07777429b91e6852d5","affiliation":"Department of Chemistry, Faculty of Science, Suez University, Suez, Egypt; Department of Analytical Chemistry, University of Valencia, C. Doctor Moliner 50, E-46100 Burjassot, Valencia, Spain","abstract":"We developed a simple self-chemical optical sensor for the monitoring and removal of ultra-trace levels of Hg(II) from aqueous media. The development of this sensor was based on the covalent attachment of amino-functionalized aluminum-based MOF particles with ninhydrin. The new sensor is densely coated with a chelating ligand to permit an ultra-fast, selective, pH-dependent visualization for removal of Hg(II) with detection limit (LOD∼0.494 μg L−1). Monitoring was accomplished via both a colorimetric signal visible to the naked eye as well as UV–vis absorption spectroscopy. Digital image-based colorimetric analysis has also used as a semi-quantitative analysis for determination the concentration of Hg(II) ions as a fast, sensitive and low-cost colorimetric detection system. Further, the new robust sensor exhibited long-term stability and high reusability. The developed sensor was also successfully applied to the determination and removal of Hg(II) from silver oxide button cells. © 2017 Elsevier B.V.","author_keywords":"Colorimetric; Electronic wastes; Mercury; MOF; Self-chemosensor","keywords":"Absorption spectroscopy; Color; Colorimetric analysis; Colorimetry; Electronic Waste; Java programming language; Physiology; Reusability, Chemosensor; Colorimetric; Colorimetric detection; Covalent attachment; Determination and removals; Long term stability; Semi-quantitative analysis; VIS absorption spectroscopy, Mercury (metal)","references":"Basu, N., Kwan, M., Chan, H.M., Mercury but not organochlorines inhibits muscarinic cholinergic receptor binding in the cerebrum of ringed seals (Phoca hispida) (2006) J. Toxicol. Environ. Health, A, 69, pp. 1133-1143; Bessbousse, H., Rhlalou, T., Verchere, J.-F., Lebrun, L.L., Removal of heavy metal ions from aqueous solutions by filtration with a novel complexing membrane containing poly (ethyleneimine) in a poly (vinyl alcohol) matrix (2008) J. Membr. Sci., 307, pp. 249-259; El-Safty, S.A., Ismail, A., Matsunaga, T., Mizukami, F., Optical nanosensor design with uniform pore geometry and large particle morphology (2007) Chem. Eur. J., 13, p. 9245; Renzoni, A., Zino, F., Franchi, E., Mercury levels along the food chain and risk for exposed populations (1998) Environ. Res., 77, pp. 68-72; Ros-Lis, J.V., Marcos, M.D., Martinez-Manez, R., Rurack, K., Soto, J., A regenerative chemodosimeter based on metal induced dye formation for the highly selective and sensitive optical determination of Hg2+ ions (2005) Angew. Chem. Int. Ed., 44, pp. 4405-4407; US EPA, Edition of the Drinking Water Standards and Health Advisories (2012), US Environmental Protection Agency Washington, DC (April, 2012, EPA 822-S-12- 001); Letelier, M.E., Lepe, A.M., Faundez, M., Salazar, J., Marin, R., Aracena, P., Speisky, H., Possible mechanisms underlying copper-induced damage in biological membranes leading to cellular toxicity (2005) Chem. Chem.-Biol. Interact., 151, pp. 71-82; Wei, Y., Gao, C., Meng, F.L., Li, H.H., Wang, L., Liu, J.H., Huang, X.J., SnO2/reduced graphene oxide nanocomposite for the simultaneous electrochemical detection of cadmium(II), lead(II), copper(II), and mercury(II): an interesting favorable mutual interference (2012) Phys. Chem. C, 116, pp. 1034-1041; Chen, J., Chen, H., Jin, X., Chen, H., Determination of ultra-trace amount methyl-, phenyl- and inorganic mercury in environmental and biological samples by liquid chromatography with inductively coupled plasma mass spectrometry after cloud point extraction preconcentration (2009) Talanta, 77, pp. 1381-1387; de Wuilloud, J.C.A., Wuilloud, R.G., Silva, M.F., Olsina, R.A., Martinez, L.D., Sensitive determination of mercury in tap water by cloud point extraction pre-concentration and flow injection-cold vapor-inductively coupled plasma optical emission spectrometry (2002) Spectrochim. Acta, B, 57, pp. 365-374; Shahat, A., Ali, E.A., El Shahat, M.F., Colorimetric determination of some toxic metal ions in post-mortembiological samples (2015) Sens. Actuators, B, 221, pp. 1027-1034; Shahat, A., Awual, M.R., Khaleque, M.A., Alam, M.Z., Naushad, M., Chowdhury, A.M.S., Large-pore diameter nano-adsorbent and its application for rapid lead(II) detection and removal from aqueous media (2015) Chem. Eng. J., 273, pp. 286-295; Rabiul Awual, M., Shadhin, M.H., Shahat, A., Functionalized novel mesoporous adsorbent for selective Lead(II) ions monitoring and removal from wastewater (2014) Sens. Actuators B, 203, p. 854; El-Safty, S.A., Shenashen, M.A., Shahat, A., Tailor-made micro-object optical sensor based on mesoporous pellets for visual monitoring and removal of toxic metal ions from aqueous media (2013) Small, 9, pp. 2288-2292; Shahat, A., Hassan, H.M.A., Azzazy, H.M.E., Optical metal-organic framework sensor for selective discrimination of some toxic metal ions in water (2013) Anal. Chim. Acta, 793, pp. 90-98; Shenashena, M.A., Shahat, A., El-Safty, S.A., Ultra-trace recognition and removal of toxic chromium (VI) ions from water using visual mesocaptor (2013) J. Haz. Mat., 244, pp. 726-735; El-Safty, S.A., Abdellatef, S., Ismael, M., Shahat, A., Optical nanosphere sensor based on shell-By-Shell fabrication for removal of toxic metals from human blood (2013) Adv. Healthcare Mater., 2, pp. 854-862; Lu, Q., Gao, F., Komarneni, S., Mallouk, T.E., Ordered SBA-15 nanorod arrays inside a porous alumina membrane (2005) J. Am. Chem. Soc., 126, pp. 8650-8651; Ferey, G., Hybrid porous solids: past, present, future (2008) Chem. Soc. Rev., 37, pp. 191-214; Tranchemontagne, D.J., Mendoza-Cortés, J.L., O'Keeffea, M., Yaghi, O.M., Secondary building units, nets and bonding in the chemistry of metal–organic frameworks (2009) Chem. Soc. Rev., 38, pp. 1257-1283; Stock, N., Biswas, S., Synthesis of metal-Organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites (2012) Chem. Rev., 112, pp. 933-969; Li, J.R., Sculley, J., Zhou, H.C., Metal-organic frameworks for separations (2012) Chem. Rev., 112, pp. 869-932; Sumida, K., Rogow, D.L., Mason, J.A., McDonald, T.M., Bloch, E.D., Herm, Z.R., Bae, T.H., Long, J.R., Carbon dioxide capture in metal-organic frameworks (2012) Chem. Rev., 112, pp. 724-781; Serra-Crespo, P., Ramos-Fernandez, E.V., Gascon, J., Kapteijn, F., Synthesis and characterization of an amino functionalized MIL-101(Al): separation and catalytic properties (2011) Chem. Mater., 23, pp. 2565-2572; Bromberg, L., Klichko, Y., Chang, E.P., Speakman, S., Straut, C.M., Wilusz, E., Hatton, T.A., Alkylaminopyridine-modified aluminum aminoterephthalate metal- organic frameworks as components of reactive self-detoxifying materials (2012) Appl. Mater. Interfaces, 4, pp. 4595-4602; Bromberg, L., Su, X., Alan Hatton, T., Aldehyde self-condensation catalysis by aluminum aminoterephthalate metal-organic frameworks modified with aluminum isopropoxide (2013) Chem. Mater., 25, pp. 1636-1642; Hartmann, M., Fischer, M., Amino-functionalized basic catalysts with MIL-101 structure (2012) Microp. Mesop. Materials, 164, pp. 38-43; Toyao, T., Fujiwaki, M., Horiuchi, Y., Matsuoka, M., Application of an amino-functionalised metal–organic framework: an approach to a one-pot acid–base reaction (2013) RSC Adv., 3, pp. 21582-21587; Haque, E., Lo, V., Minett, A.I., Harris, A.T., Church, T.L., Dichotomous adsorption behaviour of dyes on an amino-functionalised metal–organic framework, amino-MIL-101(Al) (2014) J. Mater. Chem., 2, pp. 193-203. , (A); Cheng, X., Zhang, A., Hou, K., Liu, M., Wang, Y., Song, C., Zhange, G., Guo, X., Size- and morphology-controlled NH2-MIL-53(Al) prepared in DMF–water mixed solvents (2013) Dalton Trans., 42, pp. 13698-13705; Friedman, M., The chemistry of ninhydrin (1967) Canad. J. Chem, 45, pp. 2271-2275; Llewellyn, P.L., Bourrelly, S., Serre, C., Vimont, A., Daturi, M., Hamon, L., De Weireld, G., Ferey, G., High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101 (2008) Langmuir, 24, pp. 7245-7250; Gascon, J., Aktay, U., Hernandez-Alonso, M.D., van Klink, G.P.M., Kapteijn, F., Amino-based metal-organic frameworks as stable, highly active basic catalysts (2009) J. Catal., 261, pp. 75-87; Huang, Y., Zheng, Z., Liu, T., Lü, J., Li, H., Cao, R., Palladium nanoparticles supported on amino functionalized metal-organic frameworks as highly active catalysts for the Suzuki–Miyaura cross-coupling reaction (2011) Catal. Commun., 14, pp. 27-31; Hong, D.Y., Hwang, Y.K., Serre, C., Ferey, G., Chang, J.S., Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis (2009) Adv. Funct. Mater., 19, pp. 1537-1552; Khalil, M.M.H., Shahat, A., Radwan, A., El-Shahat, M.F., Colorimetric determination of Cu (II) ions in biological samples using metal-organic framework as scaffold (2016) Sens. Actuators, B, 233, pp. 272-280; Awual, M.R., Hasan, M.M., Shahat, A., Naushad, M., Shiwaku, H., Yaita, T., Investigation of ligand immobilized nano-composite adsorbent for efficient cerium(III) detection and recovery (2015) Chem. Eng. J., 265, pp. 210-215; Christian, G.D., Analytical Chemistry (2003), 6th ed. Wiley New York; Hamza, A., Bashammakh, A.S., Al-Sibaai, A.A., Al-Saidi, H.M., El-Shahawi, M.S., Part 1. Spectrophotometric determination of trace mercury (II) in dental-unit wastewater and fertilizer samples using the novel reagent 6-hydroxy-3-(2-oxoindolin-3-ylideneamino)-2-thioxo-2H-1 3-thiazin-4(3H)-one and the dual-wavelength −correction spectrophotometry (2010) J. Hazard. Mater., 178, pp. 287-292; Jamaluddin Ahmed, M., Shah Alam, M., A rapid spectrophotometric method for the determination of mercury in environmental, biological, soil and plant samples using diphenylthiocarbazone (2003) Spectroscopy, 17, pp. 45-52; Jeoung, M.-S., Choi, H.-S., Spectrophotometric determination of trace Hg(II) in cetyltrimethylammonium bromide media (2004) Bull. Korean Chem. Soc., 25 (12), pp. 1877-1881; Nekoue, F., Nekoue, S., Spectrophotometric determination of mercury (II) by simultaneous micelle mediated extraction through ternary complex formation in water samples (2014) Orient. J. Chem., Vol., 30 (2), pp. 867-871; Loo, A.Y.Y., Lay, Y.P., Kutty, M.G., Timpe, O., Spectrophotometric determination of mercury with iodide and rhodamine B (2012) Sains Malaysiana, 41 (2), pp. 213-218; Deepa, K., Raj, Y.P., Lingappa, Y., Spectrophotometric determination of Mercury in environmental samples using 5-methylthiophene-2-carboxaldehyde ethylenediamine (MTCED) (2014) Der Pharma Chemica, 6 (3), pp. 48-55; Buszewski, B., Szultka, M., Past, present, and future of solid phase extraction: a review (2012) Crit. Rev. Anal. Chem., 42, pp. 198-213; Langmuir, I., The adsorption of gases on plane surfaces of glass, mica and platinum (1918) J. Chem. Am. Soc., 40, pp. 1361-1403; Shenashen, M.A., Elshehy, E.A., El-Safty, S.A., Khairy, M., Visual monitoring and removal of divalent copper, cadmium, and mercury ions from water by using mesoporous cubic Ia3d aluminosilica sensors (2013) Sep. Purif. Technol., 116, pp. 73-86; Girginova, P.I., da-Silva, A.L., Lopes, C.B., Figueira, P., Otero, M., Amaral, V.S., Pereira, E., Trindade, T., Silica coated magnetite particles for magnetic removal of Hg2+ from water (2010) J. Colloid Interface Sci., 345, pp. 234-240; El-Safty, S.A., Shenashen, M.A., Optical mesosensor for capturing of Fe(III) and Hg(II) ions from water and physiological fluids (2013) Sens. and Actu. B, 183, pp. 58-70; Tzvetkova, P., Nickolov, R., Modified and unmodified silica gel used for heavy metal ions removal from aqueous (2012) J. Univ. Chem. Technol. Metall., 47, pp. 498-504; Huang, C., Hu, B., Silica-coated magnetic nanoparticles modified with γ-mercaptopropyltrimethoxysilane for fast and selective solid phase extraction of trace amounts of Cd, Cu, Hg, and Pb in environmental and biological samples prior to their determination by inductively coupled plasma mass spectrometry (2008) Spectro. chim. Acta Part B, 63, pp. 437-444; Fuliu, J., Hanzhao, Z.S., Binjiang, A., Coating Fe3O4 magnetic nanoparticles with humic acid for high efficient removal of heavy metals in water (2008) Environ. Sci. Technol., 42, pp. 6949-6954; Kompany-Zareh, M., Mansourian, M., Ravaee, F., Simple method for colorimetric spot-test quantitative analysis of Fe(III) using a computer controlled hand-scanner (2002) Anal. Chim. Acta, 471, pp. 97-104; Aktas, S., Silver recovery from spent silver oxide button cells (2010) Hydrometallurgy, 104, pp. 106-111; Oh, C.J., Lee, S.O., Yang, H.S., Ha, T.J., Kim, M.J., Selective leaching of valuable metals from waste printed circuit boards (2003) J. Air Waste Manage., 53 (7), pp. 897-902","correspondence_address1":"Shahat, A.; Department of Chemistry, Egypt; email: ashahat@aucegypt.edu","publisher":"Elsevier B.V.","issn":"09254005","coden":"SABCE","language":"English","abbrev_source_title":"Sens Actuators, B Chem","document_type":"Article","source":"Scopus","bibtex":"@ARTICLE{Shahat2017164,\nauthor={Shahat, A. and Elsalam, S.A. and Herrero-Martínez, J.M. and Simó-Alfonso, E.F. and Ramis-Ramos, G.},\ntitle={Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF},\njournal={Sensors and Actuators, B: Chemical},\nyear={2017},\nvolume={253},\npages={164-172},\ndoi={10.1016/j.snb.2017.06.125},\nnote={cited By 54},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021052709&doi=10.1016%2fj.snb.2017.06.125&partnerID=40&md5=de941ee53eb0fe07777429b91e6852d5},\naffiliation={Department of Chemistry, Faculty of Science, Suez University, Suez, Egypt; Department of Analytical Chemistry, University of Valencia, C. Doctor Moliner 50, E-46100 Burjassot, Valencia, Spain},\nabstract={We developed a simple self-chemical optical sensor for the monitoring and removal of ultra-trace levels of Hg(II) from aqueous media. The development of this sensor was based on the covalent attachment of amino-functionalized aluminum-based MOF particles with ninhydrin. The new sensor is densely coated with a chelating ligand to permit an ultra-fast, selective, pH-dependent visualization for removal of Hg(II) with detection limit (LOD∼0.494 μg L−1). Monitoring was accomplished via both a colorimetric signal visible to the naked eye as well as UV–vis absorption spectroscopy. Digital image-based colorimetric analysis has also used as a semi-quantitative analysis for determination the concentration of Hg(II) ions as a fast, sensitive and low-cost colorimetric detection system. Further, the new robust sensor exhibited long-term stability and high reusability. The developed sensor was also successfully applied to the determination and removal of Hg(II) from silver oxide button cells. © 2017 Elsevier B.V.},\nauthor_keywords={Colorimetric; Electronic wastes; Mercury; MOF; Self-chemosensor},\nkeywords={Absorption spectroscopy; Color; Colorimetric analysis; Colorimetry; Electronic Waste; Java programming language; Physiology; Reusability, Chemosensor; Colorimetric; Colorimetric detection; Covalent attachment; Determination and removals; Long term stability; Semi-quantitative analysis; VIS absorption spectroscopy, Mercury (metal)},\nreferences={Basu, N., Kwan, M., Chan, H.M., Mercury but not organochlorines inhibits muscarinic cholinergic receptor binding in the cerebrum of ringed seals (Phoca hispida) (2006) J. Toxicol. Environ. 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Commun., 14, pp. 27-31; Hong, D.Y., Hwang, Y.K., Serre, C., Ferey, G., Chang, J.S., Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis (2009) Adv. Funct. Mater., 19, pp. 1537-1552; Khalil, M.M.H., Shahat, A., Radwan, A., El-Shahat, M.F., Colorimetric determination of Cu (II) ions in biological samples using metal-organic framework as scaffold (2016) Sens. Actuators, B, 233, pp. 272-280; Awual, M.R., Hasan, M.M., Shahat, A., Naushad, M., Shiwaku, H., Yaita, T., Investigation of ligand immobilized nano-composite adsorbent for efficient cerium(III) detection and recovery (2015) Chem. Eng. J., 265, pp. 210-215; Christian, G.D., Analytical Chemistry (2003), 6th ed. Wiley New York; Hamza, A., Bashammakh, A.S., Al-Sibaai, A.A., Al-Saidi, H.M., El-Shahawi, M.S., Part 1. Spectrophotometric determination of trace mercury (II) in dental-unit wastewater and fertilizer samples using the novel reagent 6-hydroxy-3-(2-oxoindolin-3-ylideneamino)-2-thioxo-2H-1 3-thiazin-4(3H)-one and the dual-wavelength −correction spectrophotometry (2010) J. Hazard. Mater., 178, pp. 287-292; Jamaluddin Ahmed, M., Shah Alam, M., A rapid spectrophotometric method for the determination of mercury in environmental, biological, soil and plant samples using diphenylthiocarbazone (2003) Spectroscopy, 17, pp. 45-52; Jeoung, M.-S., Choi, H.-S., Spectrophotometric determination of trace Hg(II) in cetyltrimethylammonium bromide media (2004) Bull. Korean Chem. Soc., 25 (12), pp. 1877-1881; Nekoue, F., Nekoue, S., Spectrophotometric determination of mercury (II) by simultaneous micelle mediated extraction through ternary complex formation in water samples (2014) Orient. J. Chem., Vol., 30 (2), pp. 867-871; Loo, A.Y.Y., Lay, Y.P., Kutty, M.G., Timpe, O., Spectrophotometric determination of mercury with iodide and rhodamine B (2012) Sains Malaysiana, 41 (2), pp. 213-218; Deepa, K., Raj, Y.P., Lingappa, Y., Spectrophotometric determination of Mercury in environmental samples using 5-methylthiophene-2-carboxaldehyde ethylenediamine (MTCED) (2014) Der Pharma Chemica, 6 (3), pp. 48-55; Buszewski, B., Szultka, M., Past, present, and future of solid phase extraction: a review (2012) Crit. Rev. Anal. Chem., 42, pp. 198-213; Langmuir, I., The adsorption of gases on plane surfaces of glass, mica and platinum (1918) J. Chem. Am. Soc., 40, pp. 1361-1403; Shenashen, M.A., Elshehy, E.A., El-Safty, S.A., Khairy, M., Visual monitoring and removal of divalent copper, cadmium, and mercury ions from water by using mesoporous cubic Ia3d aluminosilica sensors (2013) Sep. Purif. Technol., 116, pp. 73-86; Girginova, P.I., da-Silva, A.L., Lopes, C.B., Figueira, P., Otero, M., Amaral, V.S., Pereira, E., Trindade, T., Silica coated magnetite particles for magnetic removal of Hg2+ from water (2010) J. Colloid Interface Sci., 345, pp. 234-240; El-Safty, S.A., Shenashen, M.A., Optical mesosensor for capturing of Fe(III) and Hg(II) ions from water and physiological fluids (2013) Sens. and Actu. B, 183, pp. 58-70; Tzvetkova, P., Nickolov, R., Modified and unmodified silica gel used for heavy metal ions removal from aqueous (2012) J. Univ. Chem. Technol. Metall., 47, pp. 498-504; Huang, C., Hu, B., Silica-coated magnetic nanoparticles modified with γ-mercaptopropyltrimethoxysilane for fast and selective solid phase extraction of trace amounts of Cd, Cu, Hg, and Pb in environmental and biological samples prior to their determination by inductively coupled plasma mass spectrometry (2008) Spectro. chim. Acta Part B, 63, pp. 437-444; Fuliu, J., Hanzhao, Z.S., Binjiang, A., Coating Fe3O4 magnetic nanoparticles with humic acid for high efficient removal of heavy metals in water (2008) Environ. Sci. Technol., 42, pp. 6949-6954; Kompany-Zareh, M., Mansourian, M., Ravaee, F., Simple method for colorimetric spot-test quantitative analysis of Fe(III) using a computer controlled hand-scanner (2002) Anal. Chim. Acta, 471, pp. 97-104; Aktas, S., Silver recovery from spent silver oxide button cells (2010) Hydrometallurgy, 104, pp. 106-111; Oh, C.J., Lee, S.O., Yang, H.S., Ha, T.J., Kim, M.J., Selective leaching of valuable metals from waste printed circuit boards (2003) J. Air Waste Manage., 53 (7), pp. 897-902},\ncorrespondence_address1={Shahat, A.; Department of Chemistry, Egypt; email: ashahat@aucegypt.edu},\npublisher={Elsevier B.V.},\nissn={09254005},\ncoden={SABCE},\nlanguage={English},\nabbrev_source_title={Sens Actuators, B Chem},\ndocument_type={Article},\nsource={Scopus},\n}\n\n","author_short":["Shahat, A.","Elsalam, S.","Herrero-Martínez, J.","Simó-Alfonso, E.","Ramis-Ramos, G."],"key":"Shahat2017164","id":"Shahat2017164","bibbaseid":"shahat-elsalam-herreromartnez-simalfonso-ramisramos-opticalrecognitionandremovalofhgiiusinganewselfchemosensorbasedonamodifiedaminofunctionalizedalmof-2017","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021052709&doi=10.1016%2fj.snb.2017.06.125&partnerID=40&md5=de941ee53eb0fe07777429b91e6852d5"},"keyword":["Absorption spectroscopy; Color; Colorimetric analysis; Colorimetry; Electronic Waste; Java programming language; Physiology; Reusability","Chemosensor; Colorimetric; Colorimetric detection; Covalent attachment; Determination and removals; Long term stability; Semi-quantitative analysis; VIS absorption spectroscopy","Mercury (metal)"],"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://www.clecem.es/wp-content/uploads/2024/01/scopus.bib","dataSources":["z88YG74vvXjjYpRcn"],"keywords":["absorption spectroscopy; color; colorimetric analysis; colorimetry; electronic waste; java programming language; physiology; reusability","chemosensor; colorimetric; colorimetric detection; covalent attachment; determination and removals; long term stability; semi-quantitative analysis; vis absorption spectroscopy","mercury (metal)"],"search_terms":["optical","recognition","removal","using","new","self","chemosensor","based","modified","amino","functionalized","mof","shahat","elsalam","herrero-martínez","simó-alfonso","ramis-ramos"],"title":"Optical recognition and removal of Hg(II) using a new self-chemosensor based on a modified amino-functionalized Al-MOF","year":2017}