Vacuum deposition of high-quality thin films displaying spin transition near room temperature. Shalabaeva, V., Rat, S., Manrique-Juarez, M. D., Bas, A., Vendier, L., Salmon, L., Molnár, G., & Bousseksou, A. Journal of Materials Chemistry C, 5(18):4419–4425, May, 2017. Publisher: The Royal Society of Chemistry![Vacuum deposition of high-quality thin films displaying spin transition near room temperature [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex We report on [Fe(HB(tz)3)2] (tz = triazolyl) (1) thin films with thicknesses in the range of 20–200 nm, which were thermally evaporated on fused silica substrates. Using X-ray diffraction, Raman spectroscopy, UV spectrophotometry, magnetometry and atomic force microscopy, we show that the as-deposited amorphous films can be recrystallized by means of solvent–vapour annealing. The resulting crystalline films are dense, homogenous, highly oriented (with the orthorhombic c-axis normal to the substrate) and exhibit an abrupt and fully complete spin transition around 338 K for each film thickness. The films show stable morphology and spin crossover properties upon thermal cycling and also upon long-term storage in ambient air providing appealing prospects for possible applications in a range of nanoscale devices.
@article{shalabaeva_vacuum_2017,
title = {Vacuum deposition of high-quality thin films displaying spin transition near room temperature},
volume = {5},
issn = {2050-7534},
url = {https://pubs.rsc.org/en/content/articlelanding/2017/tc/c7tc00999b},
doi = {10.1039/C7TC00999B},
abstract = {We report on [Fe(HB(tz)3)2] (tz = triazolyl) (1) thin films with thicknesses in the range of 20–200 nm, which were thermally evaporated on fused silica substrates. Using X-ray diffraction, Raman spectroscopy, UV spectrophotometry, magnetometry and atomic force microscopy, we show that the as-deposited amorphous films can be recrystallized by means of solvent–vapour annealing. The resulting crystalline films are dense, homogenous, highly oriented (with the orthorhombic c-axis normal to the substrate) and exhibit an abrupt and fully complete spin transition around 338 K for each film thickness. The films show stable morphology and spin crossover properties upon thermal cycling and also upon long-term storage in ambient air providing appealing prospects for possible applications in a range of nanoscale devices.},
language = {en},
number = {18},
urldate = {2023-11-10},
journal = {Journal of Materials Chemistry C},
author = {Shalabaeva, Victoria and Rat, Sylvain and Manrique-Juarez, Maria Dolores and Bas, Alin-Ciprian and Vendier, Laure and Salmon, Lionel and Molnár, Gábor and Bousseksou, Azzedine},
month = may,
year = {2017},
note = {Publisher: The Royal Society of Chemistry},
pages = {4419--4425},
}
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