Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation (CCTP) combined with sulfur free-RAFT in emulsion polymerisation. Shegiwal, A., Wemyss, A. M., Liarou, E., Town, J., Patias, G., Atkins, C. J., Marathianos, A., Lester, D. W., Efstathiou, S., & Haddleton, D. M. EUROPEAN POLYMER JOURNAL, February, 2020. doi abstract bibtex Statistical copolymers of methacrylic acid and methyl methacrylate were synthesised via free radical catalytic chain transfer polymerisation (CCTP) in emulsion to form a hydrophilic emulsifier/surfactant. The vinyl-terminated oligomers were in turn utilised as chain transfer agents, with no further purification, for the formation of diblock copolymers with butyl and methyl methacrylate which constitutes the emulsifier via sulfur-free reversible addition-fragmentation chain transfer polymerisation (SF-RAFT). In turn these polymers were solubilized with various concentrations of ammonium hydroxide and utilised in the surfactant-free emulsion polymerization of butyl methacrylate using persulfate initiators, which also stabilized the polymer particles with observed no coagulation, with solid contents as high as 40%.
@article{shegiwal_polymerisable_2020,
title = {Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation ({CCTP}) combined with sulfur free-{RAFT} in emulsion polymerisation},
volume = {125},
issn = {0014-3057},
doi = {10.1016/j.eurpolymj.2020.109491},
abstract = {Statistical copolymers of methacrylic acid and methyl methacrylate were synthesised via free radical catalytic chain transfer polymerisation (CCTP) in emulsion to form a hydrophilic emulsifier/surfactant. The vinyl-terminated oligomers were in turn utilised as chain transfer agents, with no further purification, for the formation of diblock copolymers with butyl and methyl methacrylate which constitutes the emulsifier via sulfur-free reversible addition-fragmentation chain transfer polymerisation (SF-RAFT). In turn these polymers were solubilized with various concentrations of ammonium hydroxide and utilised in the surfactant-free emulsion polymerization of butyl methacrylate using persulfate initiators, which also stabilized the polymer particles with observed no coagulation, with solid contents as high as 40\%.},
urldate = {2020-03-24},
journal = {EUROPEAN POLYMER JOURNAL},
author = {Shegiwal, Ataulla and Wemyss, Alan M. and Liarou, Evelina and Town, James and Patias, Geogios and Atkins, Christophe J. and Marathianos, Arkadios and Lester, Daniel W. and Efstathiou, Spyridon and Haddleton, David M.},
month = feb,
year = {2020},
}
Downloads: 0
{"_id":"Xeqj7A3drjZGRLTtX","bibbaseid":"shegiwal-wemyss-liarou-town-patias-atkins-marathianos-lester-etal-polymerisablesurfactantsforpolymethacrylatesusingcatalyticchaintransferpolymerisationcctpcombinedwithsulfurfreeraftinemulsionpolymerisation-2020","author_short":["Shegiwal, A.","Wemyss, A. M.","Liarou, E.","Town, J.","Patias, G.","Atkins, C. J.","Marathianos, A.","Lester, D. W.","Efstathiou, S.","Haddleton, D. M."],"bibdata":{"bibtype":"article","type":"article","title":"Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation (CCTP) combined with sulfur free-RAFT in emulsion polymerisation","volume":"125","issn":"0014-3057","doi":"10.1016/j.eurpolymj.2020.109491","abstract":"Statistical copolymers of methacrylic acid and methyl methacrylate were synthesised via free radical catalytic chain transfer polymerisation (CCTP) in emulsion to form a hydrophilic emulsifier/surfactant. The vinyl-terminated oligomers were in turn utilised as chain transfer agents, with no further purification, for the formation of diblock copolymers with butyl and methyl methacrylate which constitutes the emulsifier via sulfur-free reversible addition-fragmentation chain transfer polymerisation (SF-RAFT). In turn these polymers were solubilized with various concentrations of ammonium hydroxide and utilised in the surfactant-free emulsion polymerization of butyl methacrylate using persulfate initiators, which also stabilized the polymer particles with observed no coagulation, with solid contents as high as 40%.","urldate":"2020-03-24","journal":"EUROPEAN POLYMER JOURNAL","author":[{"propositions":[],"lastnames":["Shegiwal"],"firstnames":["Ataulla"],"suffixes":[]},{"propositions":[],"lastnames":["Wemyss"],"firstnames":["Alan","M."],"suffixes":[]},{"propositions":[],"lastnames":["Liarou"],"firstnames":["Evelina"],"suffixes":[]},{"propositions":[],"lastnames":["Town"],"firstnames":["James"],"suffixes":[]},{"propositions":[],"lastnames":["Patias"],"firstnames":["Geogios"],"suffixes":[]},{"propositions":[],"lastnames":["Atkins"],"firstnames":["Christophe","J."],"suffixes":[]},{"propositions":[],"lastnames":["Marathianos"],"firstnames":["Arkadios"],"suffixes":[]},{"propositions":[],"lastnames":["Lester"],"firstnames":["Daniel","W."],"suffixes":[]},{"propositions":[],"lastnames":["Efstathiou"],"firstnames":["Spyridon"],"suffixes":[]},{"propositions":[],"lastnames":["Haddleton"],"firstnames":["David","M."],"suffixes":[]}],"month":"February","year":"2020","bibtex":"@article{shegiwal_polymerisable_2020,\n\ttitle = {Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation ({CCTP}) combined with sulfur free-{RAFT} in emulsion polymerisation},\n\tvolume = {125},\n\tissn = {0014-3057},\n\tdoi = {10.1016/j.eurpolymj.2020.109491},\n\tabstract = {Statistical copolymers of methacrylic acid and methyl methacrylate were synthesised via free radical catalytic chain transfer polymerisation (CCTP) in emulsion to form a hydrophilic emulsifier/surfactant. The vinyl-terminated oligomers were in turn utilised as chain transfer agents, with no further purification, for the formation of diblock copolymers with butyl and methyl methacrylate which constitutes the emulsifier via sulfur-free reversible addition-fragmentation chain transfer polymerisation (SF-RAFT). In turn these polymers were solubilized with various concentrations of ammonium hydroxide and utilised in the surfactant-free emulsion polymerization of butyl methacrylate using persulfate initiators, which also stabilized the polymer particles with observed no coagulation, with solid contents as high as 40\\%.},\n\turldate = {2020-03-24},\n\tjournal = {EUROPEAN POLYMER JOURNAL},\n\tauthor = {Shegiwal, Ataulla and Wemyss, Alan M. and Liarou, Evelina and Town, James and Patias, Geogios and Atkins, Christophe J. and Marathianos, Arkadios and Lester, Daniel W. and Efstathiou, Spyridon and Haddleton, David M.},\n\tmonth = feb,\n\tyear = {2020},\n}\n\n","author_short":["Shegiwal, A.","Wemyss, A. M.","Liarou, E.","Town, J.","Patias, G.","Atkins, C. J.","Marathianos, A.","Lester, D. W.","Efstathiou, S.","Haddleton, D. M."],"key":"shegiwal_polymerisable_2020","id":"shegiwal_polymerisable_2020","bibbaseid":"shegiwal-wemyss-liarou-town-patias-atkins-marathianos-lester-etal-polymerisablesurfactantsforpolymethacrylatesusingcatalyticchaintransferpolymerisationcctpcombinedwithsulfurfreeraftinemulsionpolymerisation-2020","role":"author","urls":{},"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://warwick.ac.uk/fac/cross_fac/wesic/research/wpg/research/WPGsep2024.bib","dataSources":["m4fxWT6XKrYfGbZFR","GBhqMC9hjyD5vqptk","6idaYK6okJY39mWgG"],"keywords":[],"search_terms":["polymerisable","surfactants","polymethacrylates","using","catalytic","chain","transfer","polymerisation","cctp","combined","sulfur","free","raft","emulsion","polymerisation","shegiwal","wemyss","liarou","town","patias","atkins","marathianos","lester","efstathiou","haddleton"],"title":"Polymerisable surfactants for polymethacrylates using catalytic chain transfer polymerisation (CCTP) combined with sulfur free-RAFT in emulsion polymerisation","year":2020}