Allylic Polymers IV. The Effect of Alkyl-Substituents on Copolymerization of Allyl Alkyl Ethers with Vinyl Acetate. Shigetomi, Y., Ono, N., Kato, H., & Oki, M. Polymer Journal, 24(3):247–255, March, 1992. Number: 3 Publisher: Nature Publishing Group![Allylic Polymers IV. The Effect of Alkyl-Substituents on Copolymerization of Allyl Alkyl Ethers with Vinyl Acetate [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex The radical copolymerization of allyl alkyl ethers with vinyl acetate has been studied in the feed range from 10 to 90 mol% allyl alkyl ethers. The following values were obtained by the Kelen-Tüdös method for the reactivity ratios: allyl ethyl ether (M1)-vinyl acetate (M2), r1=0.041±0.002, r2=1.56±0.08; allyl propyl ether (M1)-vinyl acetate (M2), r2=0.036±0.002, r2=1.39±0.07; allyl butyl ether (M1)-vinyl acetate (M2), r1=0.047±0.003, r2=1.39±0.07; allyl isopropyl ether (M1)-vinyl acetate (M2), r1=0.028±0.002, r2=1.56±0.08; allyl t-butyl ether ether(M1)-vinyl acetate (M2), r1=0.0057±0.0003, r2=1.51±0.08; The Q-e parameters were calculated from the allyl ether(M1)-vinyl acetate (M2) reactivity ratios. The e parameters of allylic monomers have been found to be nicely correlated with parameters such as Taft’s σ* constants of the alkyl group for allyl alkyl ether, 13C NMR chemical shift values of the γ carbon in the allylic monomers, and further, frR for the γ carbon of allyl group in the allylic monomers.
@article{shigetomi_allylic_1992,
title = {Allylic {Polymers} {IV}. {The} {Effect} of {Alkyl}-{Substituents} on {Copolymerization} of {Allyl} {Alkyl} {Ethers} with {Vinyl} {Acetate}},
volume = {24},
copyright = {1992 The Society of Polymer Science, Japan},
issn = {1349-0540},
url = {https://www.nature.com/articles/pj199227},
doi = {10.1295/polymj.24.247},
abstract = {The radical copolymerization of allyl alkyl ethers with vinyl acetate has been studied in the feed range from 10 to 90 mol\% allyl alkyl ethers. The following values were obtained by the Kelen-Tüdös method for the reactivity ratios: allyl ethyl ether (M1)-vinyl acetate (M2), r1=0.041±0.002, r2=1.56±0.08; allyl propyl ether (M1)-vinyl acetate (M2), r2=0.036±0.002, r2=1.39±0.07; allyl butyl ether (M1)-vinyl acetate (M2), r1=0.047±0.003, r2=1.39±0.07; allyl isopropyl ether (M1)-vinyl acetate (M2), r1=0.028±0.002, r2=1.56±0.08; allyl t-butyl ether ether(M1)-vinyl acetate (M2), r1=0.0057±0.0003, r2=1.51±0.08; The Q-e parameters were calculated from the allyl ether(M1)-vinyl acetate (M2) reactivity ratios. The e parameters of allylic monomers have been found to be nicely correlated with parameters such as Taft’s σ* constants of the alkyl group for allyl alkyl ether, 13C NMR chemical shift values of the γ carbon in the allylic monomers, and further, frR for the γ carbon of allyl group in the allylic monomers.},
language = {en},
number = {3},
urldate = {2021-02-22},
journal = {Polymer Journal},
author = {Shigetomi, Yasumasa and Ono, Naruhito and Kato, Hiroshi and Oki, Michinori},
month = mar,
year = {1992},
note = {Number: 3
Publisher: Nature Publishing Group},
pages = {247--255},
}
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