@ARTICLE{SilvaLopez20041045,
author={Silva López, C. and Nieto Faza, O. and Gregersen, B.A. and Lopez, X. and De Lera, A.R. and York, D.M.},
title={Pseudorotation of natural and chemically modified biological phosphoranes: Implications for RNA catalysis},
journal={ChemPhysChem},
year={2004},
volume={5},
number={7},
pages={1045-1049},
doi={10.1002/cphc.200400091},
abstract={Model intermediates: Catalytic mechanisms of RNA transphosphorylation are investigated by monitoring changes in the reaction rate that occur upon substitution of key phosphate oxygen atoms with sulfur atoms. The mechanisms and barriers to pseudorotation for a series of oxyphosphorane and thiophosphorane molecules are presented (see picture). Theoretical models provide detailed insight into biological phosphorous reactivity in RNA systems.},
}

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