@article{
 title = {The Temperature-Dependence of Rapid Low Temperature Reactions: Experiment, Understanding and Prediction},
 type = {article},
 year = {2006},
 pages = {137-156},
 volume = {133},
 websites = {http://www.rsc.org/ej/FD/2006/b600721j.pdf},
 id = {cda3264d-a687-3614-b2f4-855853a08689},
 created = {2014-10-08T16:28:18.000Z},
 file_attached = {false},
 profile_id = {363623ef-1990-38f1-b354-f5cdaa6548b2},
 group_id = {02267cec-5558-3876-9cfc-78d056bad5b9},
 last_modified = {2017-03-14T17:32:24.802Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {IWMSmith:faraday:2006a},
 source_type = {article},
 private_publication = {false},
 abstract = {Despite the success of the CRESU (Cinetique de Reaction en Ecoulement 
Supersonique Uniforme) method in measuring rate coefficients for neutral-- 
neutral reactions of radicals down close to the very low temperatures 
prevalent in dense interstellar clouds (ISCs), there are still many reactions 
of potential importance in the chemistry of these objects for which there 
have been no measurements of low temperature rate coefficients. One 
important class of reactions is that between atomic and molecular free 
radicals and unsaturated hydrocarbons; that is, alkynes and alkenes. Based 
on semi-empirical arguments and correlations of `room temperature' rate 
coefficients, k(298 K), for reactions of this type with the difference between 
the ionisation energy of the alkyne/alkene and the electron affinity of the 
radical, we suggest which reactions between the radicals, C(3P), O(3P), 
N(4S), CH, C2H and CN, and carbon chain molecules (Cn) and 
cyanopolyynes (HC2nCN and NCC2nCN) are likely to be fast at the 
temperature of dense ISCs. These reactions and rate coefficients have been 
incorporated into a purely gas-phase model (osu2005) of ISC chemistry. 
The results of these calculations are presented and discussed. 
},
 bibtype = {article},
 author = {Smith, I W M and Sage, A M and Donahue, N M and Herbst, E and Park, I H},
 journal = {Faraday Discuss.}
}

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One \nimportant class of reactions is that between atomic and molecular free \nradicals and unsaturated hydrocarbons; that is, alkynes and alkenes. Based \non semi-empirical arguments and correlations of `room temperature' rate \ncoefficients, k(298 K), for reactions of this type with the difference between \nthe ionisation energy of the alkyne/alkene and the electron affinity of the \nradical, we suggest which reactions between the radicals, C(3P), O(3P), \nN(4S), CH, C2H and CN, and carbon chain molecules (Cn) and \ncyanopolyynes (HC2nCN and NCC2nCN) are likely to be fast at the \ntemperature of dense ISCs. These reactions and rate coefficients have been \nincorporated into a purely gas-phase model (osu2005) of ISC chemistry. \nThe results of these calculations are presented and discussed. \n","bibtype":"article","author":"Smith, I W M and Sage, A M and Donahue, N M and Herbst, E and Park, I H","journal":"Faraday Discuss.","bibtex":"@article{\n title = {The Temperature-Dependence of Rapid Low Temperature Reactions: Experiment, Understanding and Prediction},\n type = {article},\n year = {2006},\n pages = {137-156},\n volume = {133},\n websites = {http://www.rsc.org/ej/FD/2006/b600721j.pdf},\n id = {cda3264d-a687-3614-b2f4-855853a08689},\n created = {2014-10-08T16:28:18.000Z},\n file_attached = {false},\n profile_id = {363623ef-1990-38f1-b354-f5cdaa6548b2},\n group_id = {02267cec-5558-3876-9cfc-78d056bad5b9},\n last_modified = {2017-03-14T17:32:24.802Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {IWMSmith:faraday:2006a},\n source_type = {article},\n private_publication = {false},\n abstract = {Despite the success of the CRESU (Cinetique de Reaction en Ecoulement \nSupersonique Uniforme) method in measuring rate coefficients for neutral-- \nneutral reactions of radicals down close to the very low temperatures \nprevalent in dense interstellar clouds (ISCs), there are still many reactions \nof potential importance in the chemistry of these objects for which there \nhave been no measurements of low temperature rate coefficients. One \nimportant class of reactions is that between atomic and molecular free \nradicals and unsaturated hydrocarbons; that is, alkynes and alkenes. Based \non semi-empirical arguments and correlations of `room temperature' rate \ncoefficients, k(298 K), for reactions of this type with the difference between \nthe ionisation energy of the alkyne/alkene and the electron affinity of the \nradical, we suggest which reactions between the radicals, C(3P), O(3P), \nN(4S), CH, C2H and CN, and carbon chain molecules (Cn) and \ncyanopolyynes (HC2nCN and NCC2nCN) are likely to be fast at the \ntemperature of dense ISCs. 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