Tuning dimensionality in low-dimensional electronic materials. Strouse, G., F., Scott, B., Swanson, B., I., Saxena, A., Batistić, I., Gammel, J., & Bishop, A., R. Chemical Physics Letters, 289(5-6):559-566, 1998. ![Tuning dimensionality in low-dimensional electronic materials [link]](https://bibbase.org/img/filetypes/link.svg "link")
Website abstract bibtex We demonstrate how dimensionality can be tuned in complex low-dimensional electronic materials via small perturbations in competing molecular forces. The delicate balance between molecular level forces on observed dimensionality in materials is illustrated by the 1-d to 3-d structural reorganization following deuteration of the ancillary ligands in the halogen-bridged transition-metal charge-transfer complex [Pt(en)(2)I-2][Pt(en)(2)]I-2 (PtI) where en denotes ethylenediamine. Specifically, the impact of competing forces on dimensionality is clearly demonstrated by the temperature-dependent phase transitions in perdeuterated PtI (D-PtI), where small changes in inter-and intra-sheet interactions drive mesoscopic structural changes. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
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abstract = {We demonstrate how dimensionality can be tuned in complex low-dimensional electronic materials via small perturbations in competing molecular forces. The delicate balance between molecular level forces on observed dimensionality in materials is illustrated by the 1-d to 3-d structural reorganization following deuteration of the ancillary ligands in the halogen-bridged transition-metal charge-transfer complex [Pt(en)(2)I-2][Pt(en)(2)]I-2 (PtI) where en denotes ethylenediamine. Specifically, the impact of competing forces on dimensionality is clearly demonstrated by the temperature-dependent phase transitions in perdeuterated PtI (D-PtI), where small changes in inter-and intra-sheet interactions drive mesoscopic structural changes. (C) 1998 Published by Elsevier Science B.V. All rights reserved.},
bibtype = {article},
author = {Strouse, Geoffrey F and Scott, Brian and Swanson, Basil I and Saxena, Avadh and Batistić, Ivo and Gammel, J.Tinka and Bishop, Alan R},
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