Orthogonal Cationic and Radical RAFT Polymerizations to Prepare Bottlebrush Polymers. Tanaka, J., Hakkinen, S., Boeck, P. T., Cong Yidan, Perrier, S., Sheiko, S. S., & You Wei ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 59(18):7203–7208, April, 2020. doi abstract bibtex An orthogonal combination of cationic and radical RAFT polymerizations is used to synthesize bottlebrush polymers using two distinct RAFT agents. Selective consumption of the first RAFT agent is used to control the cationic RAFT polymerization of a vinyl ether monomer bearing a secondary dormant RAFT agent, which subsequently allows side-chain polymers to be grafted from the pendant RAFT agent by a radical-mediated RAFT polymerization of a different monomer, thus completing the synthesis of bottlebrush polymers. The high efficiency and selectivity of the cationic and radical RAFT polymerizations allow both polymerizations to be conducted in one-pot tandem without intermediate purification.
@article{tanaka_orthogonal_2020,
title = {Orthogonal {Cationic} and {Radical} {RAFT} {Polymerizations} to {Prepare} {Bottlebrush} {Polymers}},
volume = {59},
issn = {1433-7851},
doi = {10.1002/anie.202000700},
abstract = {An orthogonal combination of cationic and radical RAFT polymerizations is used to synthesize bottlebrush polymers using two distinct RAFT agents. Selective consumption of the first RAFT agent is used to control the cationic RAFT polymerization of a vinyl ether monomer bearing a secondary dormant RAFT agent, which subsequently allows side-chain polymers to be grafted from the pendant RAFT agent by a radical-mediated RAFT polymerization of a different monomer, thus completing the synthesis of bottlebrush polymers. The high efficiency and selectivity of the cationic and radical RAFT polymerizations allow both polymerizations to be conducted in one-pot tandem without intermediate purification.},
number = {18},
urldate = {2020-04-29},
journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
author = {Tanaka, Joji and Hakkinen, Satu and Boeck, Parker T. and {Cong Yidan} and Perrier, Sebastien and Sheiko, Sergei S. and {You Wei}},
month = apr,
year = {2020},
pages = {7203--7208},
}
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