@article{
 title = {Kinetics and Products of the Gas-Phase Reactions of O3 With Amines and Related-Compounds},
 type = {article},
 year = {1994},
 pages = {303-320},
 volume = {20},
 id = {32010920-122d-3eac-a82b-31da879fa1be},
 created = {2015-05-08T02:32:46.000Z},
 file_attached = {false},
 profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},
 group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
 last_modified = {2015-05-08T12:57:10.000Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 source_type = {Journal Article},
 notes = {Review},
 abstract = {The kinetics and products of the gas-phase reactions of O3 with a series of aliphatic amines and related compounds have been investigated at 298 +/- 2 K and 740 Torr total pressure of air. The absolute rate constants obtained (in cm3 molecule-1 s-1 units) were: methylamine, (7A +/- 2.4) x 10(-21); dimethylamine, (1.67 +/- 0.20) x 10(-18); trimethylamine, (7.84 +/- 0.87) x 10(-18); 2-(dimethylamino)ethanol, (6.76 +/- 0.83) x 10(-18); and tetramethylhydrazine, (5.21 +/- 0.60) x 10(-18). The major products observed from the O3 reactions with the use of in situ FT-IR absorption spectroscopy were: from trimethylamine, (CH3)2NCHO, CHN=CH2 and HCHO; and from dimethylamine, CH3N=CH2, CH3NO2, and HCHO. Possible reaction mechanisms are presented and discussed.},
 bibtype = {article},
 author = {Tuazon, E C and Atkinson, R and Aschmann, S M and Arey, J},
 journal = {Research On Chemical Intermediates},
 number = {3-5}
}

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