@article{verchenko_new_2016,
	title = {New {Fe}-based layered telluride {Fe}3-δ{As}1-{yTe}2: synthesis, crystal structure and physical properties},
	issn = {1477-9226; 1477-9234},
	doi = {10.1039/C6DT02721K},
	abstract = {A new ternary telluride, Fe3-δAs1-yTe2, was synthesized from elements at 600 \${\textbackslash}circ\$C. It crystallizes in the hexagonal P63/mmc space group with the unit cell parameters a = 3.85091(9) {\textbackslash}AA and c = 17.1367(4) {\textbackslash}AA for δ = 0.3 and y = 0.04. Its layered crystal structure contains partially occupied intralayer and interlayer Fe positions, which give rise to significant nonstoichiometry: Fe3-δAs1-yTe2 was found to possess the homogeneity range of 0.25 {\textless} δ {\textless} 0.45 and y = 0.04. Regions of local vacancy ordering alternate with regions of randomly distributed vacancies; so that the ordering of Fe atoms and vacancies is not complete in the average structure. A clear evidence of the magnetic phase transition is obtained by thermodynamic measurements, Mössbauer spectroscopy, and neutron powder diffraction. Magnetic susceptibility measurements reveal weak ferromagnetism below TC = 123 K with a net moment of MS \${\textbackslash}sim\$ 0.1 μB/Fe at T = 2 K. This transition is confirmed by differential scanning calorimetry. Additionally, neutron powder diffraction indicates an onset of a complex AFM-like magnetic ordering below 100 K.},
	language = {english},
	journal = {Dalton Transactions},
	author = {Verchenko, Valeriy Yu and Sokolov, Sergey A. and Tsirlin, Alexander A. and Sobolev, Alexey V. and Presniakov, Igor A. and Bykov, Michael A. and Maria, Kirsanova and Shevelkov, Andrei V.},
	year = {2016}
}

{"_id":"h3wjG2eRXtDzLE8Yy","bibbaseid":"verchenko-sokolov-tsirlin-sobolev-presniakov-bykov-maria-shevelkov-newfebasedlayeredtelluridefe3as1yte2synthesiscrystalstructureandphysicalproperties-2016","authorIDs":[],"author_short":["Verchenko, V. Y.","Sokolov, S. A.","Tsirlin, A. A.","Sobolev, A. V.","Presniakov, I. A.","Bykov, M. A.","Maria, K.","Shevelkov, A. V."],"bibdata":{"bibtype":"article","type":"article","title":"New Fe-based layered telluride Fe3-δAs1-yTe2: synthesis, crystal structure and physical properties","issn":"1477-9226; 1477-9234","doi":"10.1039/C6DT02721K","abstract":"A new ternary telluride, Fe3-δAs1-yTe2, was synthesized from elements at 600 \\${\\textbackslash}circ\\$C. It crystallizes in the hexagonal P63/mmc space group with the unit cell parameters a = 3.85091(9) \\textbackslashAA and c = 17.1367(4) \\textbackslashAA for δ = 0.3 and y = 0.04. Its layered crystal structure contains partially occupied intralayer and interlayer Fe positions, which give rise to significant nonstoichiometry: Fe3-δAs1-yTe2 was found to possess the homogeneity range of 0.25 \\textless δ \\textless 0.45 and y = 0.04. Regions of local vacancy ordering alternate with regions of randomly distributed vacancies; so that the ordering of Fe atoms and vacancies is not complete in the average structure. A clear evidence of the magnetic phase transition is obtained by thermodynamic measurements, Mössbauer spectroscopy, and neutron powder diffraction. Magnetic susceptibility measurements reveal weak ferromagnetism below TC = 123 K with a net moment of MS \\${\\textbackslash}sim\\$ 0.1 μB/Fe at T = 2 K. This transition is confirmed by differential scanning calorimetry. Additionally, neutron powder diffraction indicates an onset of a complex AFM-like magnetic ordering below 100 K.","language":"english","journal":"Dalton Transactions","author":[{"propositions":[],"lastnames":["Verchenko"],"firstnames":["Valeriy","Yu"],"suffixes":[]},{"propositions":[],"lastnames":["Sokolov"],"firstnames":["Sergey","A."],"suffixes":[]},{"propositions":[],"lastnames":["Tsirlin"],"firstnames":["Alexander","A."],"suffixes":[]},{"propositions":[],"lastnames":["Sobolev"],"firstnames":["Alexey","V."],"suffixes":[]},{"propositions":[],"lastnames":["Presniakov"],"firstnames":["Igor","A."],"suffixes":[]},{"propositions":[],"lastnames":["Bykov"],"firstnames":["Michael","A."],"suffixes":[]},{"propositions":[],"lastnames":["Maria"],"firstnames":["Kirsanova"],"suffixes":[]},{"propositions":[],"lastnames":["Shevelkov"],"firstnames":["Andrei","V."],"suffixes":[]}],"year":"2016","bibtex":"@article{verchenko_new_2016,\n\ttitle = {New {Fe}-based layered telluride {Fe}3-δ{As}1-{yTe}2: synthesis, crystal structure and physical properties},\n\tissn = {1477-9226; 1477-9234},\n\tdoi = {10.1039/C6DT02721K},\n\tabstract = {A new ternary telluride, Fe3-δAs1-yTe2, was synthesized from elements at 600 \\${\\textbackslash}circ\\$C. It crystallizes in the hexagonal P63/mmc space group with the unit cell parameters a = 3.85091(9) {\\textbackslash}AA and c = 17.1367(4) {\\textbackslash}AA for δ = 0.3 and y = 0.04. Its layered crystal structure contains partially occupied intralayer and interlayer Fe positions, which give rise to significant nonstoichiometry: Fe3-δAs1-yTe2 was found to possess the homogeneity range of 0.25 {\\textless} δ {\\textless} 0.45 and y = 0.04. Regions of local vacancy ordering alternate with regions of randomly distributed vacancies; so that the ordering of Fe atoms and vacancies is not complete in the average structure. A clear evidence of the magnetic phase transition is obtained by thermodynamic measurements, Mössbauer spectroscopy, and neutron powder diffraction. Magnetic susceptibility measurements reveal weak ferromagnetism below TC = 123 K with a net moment of MS \\${\\textbackslash}sim\\$ 0.1 μB/Fe at T = 2 K. This transition is confirmed by differential scanning calorimetry. Additionally, neutron powder diffraction indicates an onset of a complex AFM-like magnetic ordering below 100 K.},\n\tlanguage = {english},\n\tjournal = {Dalton Transactions},\n\tauthor = {Verchenko, Valeriy Yu and Sokolov, Sergey A. and Tsirlin, Alexander A. and Sobolev, Alexey V. and Presniakov, Igor A. and Bykov, Michael A. and Maria, Kirsanova and Shevelkov, Andrei V.},\n\tyear = {2016}\n}\n\n","author_short":["Verchenko, V. Y.","Sokolov, S. A.","Tsirlin, A. A.","Sobolev, A. V.","Presniakov, I. A.","Bykov, M. A.","Maria, K.","Shevelkov, A. 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