Electron spectroscopy characterization of an activated ruthenium electrode. Vuković, M., Valla, T., & Milun, M. Journal of Electroanalytical Chemistry, 356(1-2):81-91, 1993.
Website abstract bibtex X-ray photoelectron spectroscopy and Auger electron spectroscopy were used for the characterization of an electrodeposited ruthenium electrode (unactivated) and an electrode subjected to electrochemical activation. The characterization was performed at room temperature and after 30 min of annealing at 400, 520 and 640 K. It was found that, at room temperature, both electrodes consist of a mixture of ruthenium oxides, hydroxides and adsorbed water molecules. In addition, carbon, sulphur and chlorine were identified as impurities. The most prominent difference between the samples is a significantly higher hydroxyl content in the case of the activated electrode. A model involving hydroxyl groups in the Ru(III)-Ru(IV) redox process is proposed. © 1993.
@article{
title = {Electron spectroscopy characterization of an activated ruthenium electrode},
type = {article},
year = {1993},
identifiers = {[object Object]},
pages = {81-91},
volume = {356},
websites = {http://linkinghub.elsevier.com/retrieve/pii/002207289380512G},
id = {01574041-0d36-39ac-b873-bf6843ed6afd},
created = {2016-11-30T14:26:34.000Z},
file_attached = {false},
profile_id = {12182ba0-f80b-33ff-8da5-1813b38b682d},
group_id = {49ce86ba-a52a-36eb-a7fb-9e42f732edd5},
last_modified = {2017-03-14T17:25:32.499Z},
read = {false},
starred = {false},
authored = {false},
confirmed = {true},
hidden = {false},
citation_key = {Vukovic1993},
source_type = {article},
private_publication = {false},
abstract = {X-ray photoelectron spectroscopy and Auger electron spectroscopy were used for the characterization of an electrodeposited ruthenium electrode (unactivated) and an electrode subjected to electrochemical activation. The characterization was performed at room temperature and after 30 min of annealing at 400, 520 and 640 K. It was found that, at room temperature, both electrodes consist of a mixture of ruthenium oxides, hydroxides and adsorbed water molecules. In addition, carbon, sulphur and chlorine were identified as impurities. The most prominent difference between the samples is a significantly higher hydroxyl content in the case of the activated electrode. A model involving hydroxyl groups in the Ru(III)-Ru(IV) redox process is proposed. © 1993.},
bibtype = {article},
author = {Vuković, Marijan and Valla, Tonica and Milun, Milorad},
journal = {Journal of Electroanalytical Chemistry},
number = {1-2}
}
Downloads: 0
{"_id":"8S8xPuKY9EHhQcN6L","bibbaseid":"vukovi-valla-milun-electronspectroscopycharacterizationofanactivatedrutheniumelectrode-1993","downloads":0,"creationDate":"2016-11-30T14:27:55.499Z","title":"Electron spectroscopy characterization of an activated ruthenium electrode","author_short":["Vuković, M.","Valla, T.","Milun, M."],"year":1993,"bibtype":"article","biburl":null,"bibdata":{"title":"Electron spectroscopy characterization of an activated ruthenium electrode","type":"article","year":"1993","identifiers":"[object Object]","pages":"81-91","volume":"356","websites":"http://linkinghub.elsevier.com/retrieve/pii/002207289380512G","id":"01574041-0d36-39ac-b873-bf6843ed6afd","created":"2016-11-30T14:26:34.000Z","file_attached":false,"profile_id":"12182ba0-f80b-33ff-8da5-1813b38b682d","group_id":"49ce86ba-a52a-36eb-a7fb-9e42f732edd5","last_modified":"2017-03-14T17:25:32.499Z","read":false,"starred":false,"authored":false,"confirmed":"true","hidden":false,"citation_key":"Vukovic1993","source_type":"article","private_publication":false,"abstract":"X-ray photoelectron spectroscopy and Auger electron spectroscopy were used for the characterization of an electrodeposited ruthenium electrode (unactivated) and an electrode subjected to electrochemical activation. The characterization was performed at room temperature and after 30 min of annealing at 400, 520 and 640 K. It was found that, at room temperature, both electrodes consist of a mixture of ruthenium oxides, hydroxides and adsorbed water molecules. In addition, carbon, sulphur and chlorine were identified as impurities. The most prominent difference between the samples is a significantly higher hydroxyl content in the case of the activated electrode. A model involving hydroxyl groups in the Ru(III)-Ru(IV) redox process is proposed. © 1993.","bibtype":"article","author":"Vuković, Marijan and Valla, Tonica and Milun, Milorad","journal":"Journal of Electroanalytical Chemistry","number":"1-2","bibtex":"@article{\n title = {Electron spectroscopy characterization of an activated ruthenium electrode},\n type = {article},\n year = {1993},\n identifiers = {[object Object]},\n pages = {81-91},\n volume = {356},\n websites = {http://linkinghub.elsevier.com/retrieve/pii/002207289380512G},\n id = {01574041-0d36-39ac-b873-bf6843ed6afd},\n created = {2016-11-30T14:26:34.000Z},\n file_attached = {false},\n profile_id = {12182ba0-f80b-33ff-8da5-1813b38b682d},\n group_id = {49ce86ba-a52a-36eb-a7fb-9e42f732edd5},\n last_modified = {2017-03-14T17:25:32.499Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {Vukovic1993},\n source_type = {article},\n private_publication = {false},\n abstract = {X-ray photoelectron spectroscopy and Auger electron spectroscopy were used for the characterization of an electrodeposited ruthenium electrode (unactivated) and an electrode subjected to electrochemical activation. The characterization was performed at room temperature and after 30 min of annealing at 400, 520 and 640 K. It was found that, at room temperature, both electrodes consist of a mixture of ruthenium oxides, hydroxides and adsorbed water molecules. In addition, carbon, sulphur and chlorine were identified as impurities. The most prominent difference between the samples is a significantly higher hydroxyl content in the case of the activated electrode. A model involving hydroxyl groups in the Ru(III)-Ru(IV) redox process is proposed. © 1993.},\n bibtype = {article},\n author = {Vuković, Marijan and Valla, Tonica and Milun, Milorad},\n journal = {Journal of Electroanalytical Chemistry},\n number = {1-2}\n}","author_short":["Vuković, M.","Valla, T.","Milun, M."],"urls":{"Website":"http://linkinghub.elsevier.com/retrieve/pii/002207289380512G"},"bibbaseid":"vukovi-valla-milun-electronspectroscopycharacterizationofanactivatedrutheniumelectrode-1993","role":"author","downloads":0},"search_terms":["electron","spectroscopy","characterization","activated","ruthenium","electrode","vuković","valla","milun"],"keywords":[],"authorIDs":[]}