@article{
 title = {Photophysics of linear and bent p-conjugated oligomers incorporating MLCT chromophores},
 type = {article},
 year = {2000},
 pages = {INOR-545},
 id = {630f72ef-cbb1-30ff-b39a-3ad249625823},
 created = {2012-06-10T19:41:58.000Z},
 file_attached = {false},
 profile_id = {3e7260a9-6e8d-3223-930b-f5ea025e6d3f},
 last_modified = {2015-05-20T13:35:05.000Z},
 read = {false},
 starred = {false},
 authored = {true},
 confirmed = {true},
 hidden = {false},
 citation_key = {Walters2000a},
 source_type = {Journal Article},
 abstract = {Two new series of p-conjugated oligomers have been synthesized with an areneethynylene repeat structure that incorporates a 2,2'-bipyridyl subunit for inorg. MLCT chromophore ligation. The 5-LP oligomers and 5-ReP -ReI(CO)3Cl complexes are similar to a previously reported oligomer series that contains biphenyl rather than monophenyl repeat units. The 4-L oligomers and 4-Re rhenium complexes are substituted at the 4,4' positions of the central bipyridine, creating a \"bent\" oligomer. A detailed study of the oligomer and rhenium complex photophysics has been performed, and several of these results are presented. Of key interest is a temp.-dependent excited-state equil. between an oligomer-based 3p,p* state and a metal-to-ligand charge transfer (3MLCT) state. This equil. is revealed when the 3MLCT energy is raised with the use of the -ReI(CO)3(NCCH3) chromophore. [on SciFinder (R)]},
 bibtype = {article},
 author = {Walters, Keith A and Ley, Kevin D and Schanze, Kirk S},
 journal = {Abstracts of Papers, 220th ACS National Meeting, Washington, DC, United States, August 20-24, 2000}
}

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