An electrochemical Hofmann rearrangement on acrylamide copolymers. Wang, M. & Wilson, P. POLYMER CHEMISTRY, 14(26):3057–3062, July, 2023. doi abstract bibtex The primary amide side-chain of acrylamide copolymers has been utilised as an isocyanate surrogate. The isocyanate is formed under mild conditions via an electrochemical Hofmann rearrangement resulting in the formation of O-alkyl carbamate side-chains in alcohol solvents. This represents a new strategy for the modification of amide-functionalised (co)polymers.
@article{wang_electrochemical_2023,
title = {An electrochemical {Hofmann} rearrangement on acrylamide copolymers},
volume = {14},
issn = {1759-9954},
doi = {10.1039/d3py00594a},
abstract = {The primary amide side-chain of acrylamide copolymers has been utilised as an isocyanate surrogate. The isocyanate is formed under mild conditions via an electrochemical Hofmann rearrangement resulting in the formation of O-alkyl carbamate side-chains in alcohol solvents. This represents a new strategy for the modification of amide-functionalised (co)polymers.},
number = {26},
urldate = {2023-07-10},
journal = {POLYMER CHEMISTRY},
author = {Wang, Muzhao and Wilson, Paul},
month = jul,
year = {2023},
pages = {3057--3062},
}
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