@article{Watarai2009,
	title = {Measuring the optical chirality of molecular aggregates at liquid-liquid interfaces.},
	volume = {395},
	issn = {1618-2650},
	url = {http://www.ncbi.nlm.nih.gov/pubmed/19727689},
	doi = {10.1007/s00216-009-3012-5},
	abstract = {Some new experimental methods for measuring the optical chirality of molecular aggregates formed at liquid-liquid interfaces have been reviewed. Chirality measurements of interfacial aggregates are highly important not only in analytical spectroscopy but also in biochemistry and surface nanochemistry. Among these methods, a centrifugal liquid membrane method was shown to be a highly versatile method for measuring the optical chirality of the liquid-liquid interface when used in combination with a commercially available circular dichroism (CD) spectropolarimeter, provided that the interfacial aggregate exhibited a large molar absorptivity. Therefore, porphyrin and phthalocyanine were used as chromophoric probes of the chirality of itself or guest molecules at the interface. A microscopic CD method was also demonstrated for the measurement of a small region of a film or a sheet sample. In addition, second-harmonic generation and Raman scattering methods were reviewed as promising methods for detecting interfacial optical molecules and measuring bond distortions of chiral molecules, respectively.},
	number = {4},
	journal = {Analytical and bioanalytical chemistry},
	author = {Watarai, Hitoshi and Adachi, Kenta},
	month = oct,
	year = {2009},
	pmid = {19727689},
	keywords = {\#nosource, Indoles, Indoles: analysis, Optics and Photonics, Porphyrins, Porphyrins: analysis, Spectrum Analysis, Surface Properties},
	pages = {1033--46},
}

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