Low-power decoupling at high spinning frequencies in high static fields. Weingarth, M., Bodenhausen, G., & Tekely, P. Journal of magnetic resonance (San Diego, Calif. : 1997), 199(2):238–241, 2009.
Paper doi abstract bibtex We demonstrate that heteronuclear decoupling using a Phase-Inverted Supercycled Sequence for Attenuation of Rotary ResOnance (PISSARRO) is very efficient at high spinning frequencies (nu(rot)=60kHz) and high magnetic fields (900MHz for protons at 21T) even with moderate radio-frequency decoupling amplitudes (nu(1)(I)=15kHz), despite the wide range of isotropic chemical shifts of the protons and the increased effect of their chemical shift anisotropy.
@article{Weingarth2009,
title = {Low-power decoupling at high spinning frequencies in high static fields.},
volume = {199},
issn = {1096-0856},
url = {http://www.ncbi.nlm.nih.gov/pubmed/19467891},
doi = {10.1016/j.jmr.2009.04.015},
abstract = {We demonstrate that heteronuclear decoupling using a Phase-Inverted Supercycled Sequence for Attenuation of Rotary ResOnance (PISSARRO) is very efficient at high spinning frequencies (nu(rot)=60kHz) and high magnetic fields (900MHz for protons at 21T) even with moderate radio-frequency decoupling amplitudes (nu(1)(I)=15kHz), despite the wide range of isotropic chemical shifts of the protons and the increased effect of their chemical shift anisotropy.},
number = {2},
journal = {Journal of magnetic resonance (San Diego, Calif. : 1997)},
author = {Weingarth, Markus and Bodenhausen, Geoffrey and Tekely, Piotr},
year = {2009},
pmid = {19467891},
keywords = {\#nosource, Algorithms, Biomolecular, Biomolecular: methods, Chemical, Computer Simulation, Electromagnetic Fields, Models, Nuclear Magnetic Resonance, Spin Labels, Static Electricity},
pages = {238--241},
}
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