Determination of short-range order in TiVNbHf(Al). Xu, M., Wei, S., Tasan, C C., & LeBeau, J. M Appl. Phys. Lett., 122:181901, AIP Publishing, 1 May, 2023. doi abstract bibtex The presence of short-range chemical order can be a key factor in determining the mechanical behavior of metals, but directly and unambiguously determining its distribution in complex concentrated alloy systems can be challenging. Here, we directly identify and quantify chemical order in the globally single phase BCC-TiVNbHf(Al) system using aberration corrected scanning transmission electron microscopy (STEM) paired with spatial statistics methods. To overcome the difficulties of short-range order (SRO) quantification with STEM when the components of an alloy exhibit large atomic number differences and near equiatomic ratios, ``null hypothesis'' tests are used to separate experiment from a random chemical distribution. Experiment is found to deviate from both the case of an ideal random solid solution and a fully ordered structure with statistical significance. We also identify local chemical order in TiVNbHf and confirm and quantify the enhancement of SRO with the addition of Al. These results provide insight into local chemical order in the promising TiVNbHf(Al) refractory alloys while highlighting the utility of spatial statistics in characterizing nanoscale SRO in compositionally complex systems.
@ARTICLE{Xu2023-hl,
title = "Determination of short-range order in {TiVNbHf}(Al)",
author = "Xu, Michael and Wei, Shaolou and Tasan, C Cem and LeBeau, James M",
journal = "Appl. Phys. Lett.",
publisher = "AIP Publishing",
volume = 122,
pages = 181901,
abstract = "The presence of short-range chemical order can be a key factor in
determining the mechanical behavior of metals, but directly and
unambiguously determining its distribution in complex
concentrated alloy systems can be challenging. Here, we directly
identify and quantify chemical order in the globally single phase
BCC-TiVNbHf(Al) system using aberration corrected scanning
transmission electron microscopy (STEM) paired with spatial
statistics methods. To overcome the difficulties of short-range
order (SRO) quantification with STEM when the components of an
alloy exhibit large atomic number differences and near equiatomic
ratios, ``null hypothesis'' tests are used to separate experiment
from a random chemical distribution. Experiment is found to
deviate from both the case of an ideal random solid solution and
a fully ordered structure with statistical significance. We also
identify local chemical order in TiVNbHf and confirm and quantify
the enhancement of SRO with the addition of Al. These results
provide insight into local chemical order in the promising
TiVNbHf(Al) refractory alloys while highlighting the utility of
spatial statistics in characterizing nanoscale SRO in
compositionally complex systems.",
month = "1~" # may,
year = 2023,
keywords = "LeBeau Group",
doi = "10.1063/5.0145289"
}
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