@ARTICLE{Yeste20085107,
author={Yeste, M.P. and Hernández, J.C. and Trasobares, S. and Bernal, S. and Blanco, G. and Calvino, J.J. and Pérez-Omil, J.A. and Pintado, J.M.},
title={First stage of thermal aging under oxidizing conditions of a Ce 0.62Zr0.38O2 mixed oxide with an ordered cationic sublattice: A chemical, nanostructural, and nanoanalytical study},
journal={Chemistry of Materials},
year={2008},
volume={20},
number={15},
pages={5107-5113},
doi={10.1021/cm800928p},
note={cited By 23},
url={https://www.scopus.com/inward/record.url?eid=2-s2.0-50249129711&partnerID=40&md5=aef34657801f377302173c753861ea63},
affiliation={Departamento de Ciencia de Los Materiales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Rio San Pedro, Puerto Real, E-11510-Cádiz, Spain},
abstract={After being heated in a flow of 5% O2/He, at 1073 or 1123 K for 30 min, a Ce0.62Zr0.38O2 sample showing an ordered cationic sublattice had very subtle surface nanostructural changes induced on it. In parallel with them, a significant loss of low-temperature (77 < 773 K) oxygen storage capacity (OSC), with no modification of its high-temperature (T > 973 K) redox response, was observed. These nanostructural and chemical features characterize the very first stage of the process leading to the destruction of the ordered Ce-Zr sublattice, a structural phenomenon playing a key role in the control of redox behavior of ceria-zirconia mixed oxides. The reported results, including OSC, hydrogen chemisorption, and nanostructural and nanoanalytical data, lend further support to a model providing a comprehensive interpretation of the complex relationship linking thermal aging conditions, nanostructural properties, surface chemistry, and redox behavior in these materials. © 2008 American Chemical Society.},
document_type={Article},
source={Scopus},
}

{"_id":{"_str":"538ed482ad1373bf27000c4c"},"__v":0,"authorIDs":[],"author_short":["Yeste, M.","Hernández, J.","Trasobares, S.","Bernal, S.","Blanco, G.","Calvino, J.","Pérez-Omil, J.","Pintado, J."],"bibbaseid":"yeste-hernndez-trasobares-bernal-blanco-calvino-prezomil-pintado-firststageofthermalagingunderoxidizingconditionsoface062zr038o2mixedoxidewithanorderedcationicsublatticeachemicalnanostructuralandnanoanalyticalstudy-2008","bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Yeste"],"firstnames":["M.P."],"suffixes":[]},{"propositions":[],"lastnames":["Hernández"],"firstnames":["J.C."],"suffixes":[]},{"propositions":[],"lastnames":["Trasobares"],"firstnames":["S."],"suffixes":[]},{"propositions":[],"lastnames":["Bernal"],"firstnames":["S."],"suffixes":[]},{"propositions":[],"lastnames":["Blanco"],"firstnames":["G."],"suffixes":[]},{"propositions":[],"lastnames":["Calvino"],"firstnames":["J.J."],"suffixes":[]},{"propositions":[],"lastnames":["Pérez-Omil"],"firstnames":["J.A."],"suffixes":[]},{"propositions":[],"lastnames":["Pintado"],"firstnames":["J.M."],"suffixes":[]}],"title":"First stage of thermal aging under oxidizing conditions of a Ce 0.62Zr0.38O2 mixed oxide with an ordered cationic sublattice: A chemical, nanostructural, and nanoanalytical study","journal":"Chemistry of Materials","year":"2008","volume":"20","number":"15","pages":"5107-5113","doi":"10.1021/cm800928p","note":"cited By 23","url":"https://www.scopus.com/inward/record.url?eid=2-s2.0-50249129711&partnerID=40&md5=aef34657801f377302173c753861ea63","affiliation":"Departamento de Ciencia de Los Materiales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Rio San Pedro, Puerto Real, E-11510-Cádiz, Spain","abstract":"After being heated in a flow of 5% O2/He, at 1073 or 1123 K for 30 min, a Ce0.62Zr0.38O2 sample showing an ordered cationic sublattice had very subtle surface nanostructural changes induced on it. In parallel with them, a significant loss of low-temperature (77 < 773 K) oxygen storage capacity (OSC), with no modification of its high-temperature (T > 973 K) redox response, was observed. These nanostructural and chemical features characterize the very first stage of the process leading to the destruction of the ordered Ce-Zr sublattice, a structural phenomenon playing a key role in the control of redox behavior of ceria-zirconia mixed oxides. The reported results, including OSC, hydrogen chemisorption, and nanostructural and nanoanalytical data, lend further support to a model providing a comprehensive interpretation of the complex relationship linking thermal aging conditions, nanostructural properties, surface chemistry, and redox behavior in these materials. © 2008 American Chemical Society.","document_type":"Article","source":"Scopus","bibtex":"@ARTICLE{Yeste20085107,\r\nauthor={Yeste, M.P. and Hernández, J.C. and Trasobares, S. and Bernal, S. and Blanco, G. and Calvino, J.J. and Pérez-Omil, J.A. and Pintado, J.M.},\r\ntitle={First stage of thermal aging under oxidizing conditions of a Ce 0.62Zr0.38O2 mixed oxide with an ordered cationic sublattice: A chemical, nanostructural, and nanoanalytical study},\r\njournal={Chemistry of Materials},\r\nyear={2008},\r\nvolume={20},\r\nnumber={15},\r\npages={5107-5113},\r\ndoi={10.1021/cm800928p},\r\nnote={cited By 23},\r\nurl={https://www.scopus.com/inward/record.url?eid=2-s2.0-50249129711&partnerID=40&md5=aef34657801f377302173c753861ea63},\r\naffiliation={Departamento de Ciencia de Los Materiales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Rio San Pedro, Puerto Real, E-11510-Cádiz, Spain},\r\nabstract={After being heated in a flow of 5% O2/He, at 1073 or 1123 K for 30 min, a Ce0.62Zr0.38O2 sample showing an ordered cationic sublattice had very subtle surface nanostructural changes induced on it. In parallel with them, a significant loss of low-temperature (77 < 773 K) oxygen storage capacity (OSC), with no modification of its high-temperature (T > 973 K) redox response, was observed. These nanostructural and chemical features characterize the very first stage of the process leading to the destruction of the ordered Ce-Zr sublattice, a structural phenomenon playing a key role in the control of redox behavior of ceria-zirconia mixed oxides. The reported results, including OSC, hydrogen chemisorption, and nanostructural and nanoanalytical data, lend further support to a model providing a comprehensive interpretation of the complex relationship linking thermal aging conditions, nanostructural properties, surface chemistry, and redox behavior in these materials. © 2008 American Chemical Society.},\r\ndocument_type={Article},\r\nsource={Scopus},\r\n}\r\n\r\n","author_short":["Yeste, M.","Hernández, J.","Trasobares, S.","Bernal, S.","Blanco, G.","Calvino, J.","Pérez-Omil, J.","Pintado, J."],"key":"Yeste20085107","id":"Yeste20085107","bibbaseid":"yeste-hernndez-trasobares-bernal-blanco-calvino-prezomil-pintado-firststageofthermalagingunderoxidizingconditionsoface062zr038o2mixedoxidewithanorderedcationicsublatticeachemicalnanostructuralandnanoanalyticalstudy-2008","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.url?eid=2-s2.0-50249129711&partnerID=40&md5=aef34657801f377302173c753861ea63"},"downloads":0,"html":"","metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"http://www2.uca.es/dept/cmat_qinor/nanomat/people/GROUP.bib","downloads":0,"keywords":[],"search_terms":["first","stage","thermal","aging","under","oxidizing","conditions","62zr0","38o2","mixed","oxide","ordered","cationic","sublattice","chemical","nanostructural","nanoanalytical","study","yeste","hernández","trasobares","bernal","blanco","calvino","pérez-omil","pintado"],"title":"First stage of thermal aging under oxidizing conditions of a Ce 0.62Zr0.38O2 mixed oxide with an ordered cationic sublattice: A chemical, nanostructural, and nanoanalytical study","year":2008,"dataSources":["BraPrFTJMD8Pu6SQ6"]}