Rational design of nanostructured, noble metal free, ceria-zirconia catalysts with outstanding low temperature oxygen storage capacity. Yeste, M., Hernández-Garrido, J., Arias, D., Blanco, G., Rodriguez-Izquierdo, J., Pintado, J., Bernal, S., Perez-Omil, J., & Calvino, J. J. Mater. Chem. A, 2013(1):4836–4844, The Royal Society of Chemistry, 2013.
Paper doi abstract bibtex On the basis of detailed previous knowledge about the correlation existing between the Oxygen Storage Capacity (OSC) of ceria-zirconia mixed oxides, the nature of redox pretreatments and the nanostructure of this family of complex materials, it has been possible to design a synthetic strategy allowing one to prepare ceria-zirconia and ceria-yttria-doped zirconia materials, with total ceria contents below 20%, featuring OSC values higher than those observed for catalysts which incorporate supported noble metal particles in their formulation, especially in the very low, 373-473 K, temperature range. These novel, noble-metal free and highly reducible, ceria-zirconia materials allow a much more efficient usage of ceria as a component of oxygen storage formulations, which is nowadays considered one of the key innovation targets in the field of lanthanide oxide based catalysts.
@article{C3TA00016H,
abstract = {On the basis of detailed previous knowledge about the correlation existing between the Oxygen Storage Capacity (OSC) of ceria-zirconia mixed oxides, the nature of redox pretreatments and the nanostructure of this family of complex materials, it has been possible to design a synthetic strategy allowing one to prepare ceria-zirconia and ceria-yttria-doped zirconia materials, with total ceria contents below 20%, featuring OSC values higher than those observed for catalysts which incorporate supported noble metal particles in their formulation, especially in the very low, 373-473 K, temperature range. These novel, noble-metal free and highly reducible, ceria-zirconia materials allow a much more efficient usage of ceria as a component of oxygen storage formulations, which is nowadays considered one of the key innovation targets in the field of lanthanide oxide based catalysts.},
author = {Yeste, MP. and Hern\'{a}ndez-Garrido, JC. and Arias, DC. and Blanco, G. and Rodriguez-Izquierdo, JM. and Pintado, JM. and Bernal, S. and Perez-Omil, JA. and Calvino, JJ.},
doi = {10.1039/C3TA00016H},
file = {:L\:/Pagina Web/Plantillas/Prueba/Publications/PDF/c3ta00016h.pdf:pdf},
journal = {J. Mater. Chem. A},
number = {1},
pages = {4836--4844},
publisher = {The Royal Society of Chemistry},
title = {{Rational design of nanostructured, noble metal free, ceria-zirconia catalysts with outstanding low temperature oxygen storage capacity}},
url = {http://dx.doi.org/10.1039/C3TA00016H},
volume = {2013},
year = {2013}
}
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