Local and inter-regional contributions to PM2.5 nitrate and sulfate in China. Ying, Q., Wu, L., & Zhang, H. ATMOSPHERIC ENVIRONMENT, 94:582-592, PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND, SEP, 2014. doi abstract bibtex Emissions of NOx, SO2 and primary nitrate and sulfate from seven regions in China (North, Northeast, East, Central, South, Southwest and Northwest) were separately tracked in a source-oriented Community Multiscale Air Quality (CMAQ) model to quantify the local and inter-regional contributions to PM2.5 nitrate and sulfate concentrations in different cities and provinces. In January, high concentrations of nitrate (similar to 30 mu g m(-3)) occurred in the North China Plain (NCP) and the Middle and Lower Yangtze Plain (MLYP), as well as the Sichuan Basin. NOx emissions from North, Central and East China were transported over long distances to form rather uniform concentration of nitrate in the NCP and MLYP regions and significantly impacted nitrate concentrations in downwind regions as far as the Pearl River Delta (PRD) region in South China. Wintertime sulfate concentrations demonstrated a more significant inter-regional southward transport pattern and wider spatial distributions than nitrate. The top-five ranked provinces with combined nitrate and sulfate concentrations (Chongqing, Sichuan, Guizhou, Anhui and Hunan) were all affected by emissions from the North, Central and East China, in addition to their local region emissions. In August, slower northerly and northeasterly wind reduced inter-regional transport. Nitrate and sulfate concentrations peaked in North China as dilution was more severely restricted by mountain ranges further north. Three of the top five high concentration provinces (Tianjin, Hebei and Beijing) were located in North China and had more than 55% of local region contributions. Emissions from North China accounted for similar to 20% in the remaining two provinces (Shandong in East China and Henan in Central China). In addition to emissions from North China, similar to 30% or more of the nitrate and sulfate concentrations in four of the top five high concentration provinces (Tianjin, Henan, Hebei and Shandong) were due to emissions from East China. Time series of daily regional contributions in three megacities (Beijing, Shanghai and Chongqing) and a large city cluster (PRD) also indicated stronger and more frequent inter-regional transport in winter than in summer. Although the cities were mostly affected by local region emissions, influences of long range transport were especially obvious for sulfate concentration in the PRD region in winter, where emissions from North, East and Central China often accounted for more than 80% of the total concentrations. The results from this study suggest that provincial or region-level emission controls alone may not be sufficient to effectively reduce nitrate and sulfate concentrations in many areas and coordinated local and inter-regional emission control strategies are necessary for the country. (C) 2014 Elsevier Ltd. All rights reserved.
@article{ WOS:000340316300063,
Author = {Ying, Qi and Wu, Li and Zhang, Hongliang},
Title = {{Local and inter-regional contributions to PM2.5 nitrate and sulfate in
China}},
Journal = {{ATMOSPHERIC ENVIRONMENT}},
Year = {{2014}},
Volume = {{94}},
Pages = {{582-592}},
Month = {{SEP}},
Abstract = {{Emissions of NOx, SO2 and primary nitrate and sulfate from seven regions
in China (North, Northeast, East, Central, South, Southwest and
Northwest) were separately tracked in a source-oriented Community
Multiscale Air Quality (CMAQ) model to quantify the local and
inter-regional contributions to PM2.5 nitrate and sulfate concentrations
in different cities and provinces. In January, high concentrations of
nitrate (similar to 30 mu g m(-3)) occurred in the North China Plain
(NCP) and the Middle and Lower Yangtze Plain (MLYP), as well as the
Sichuan Basin. NOx emissions from North, Central and East China were
transported over long distances to form rather uniform concentration of
nitrate in the NCP and MLYP regions and significantly impacted nitrate
concentrations in downwind regions as far as the Pearl River Delta (PRD)
region in South China. Wintertime sulfate concentrations demonstrated a
more significant inter-regional southward transport pattern and wider
spatial distributions than nitrate. The top-five ranked provinces with
combined nitrate and sulfate concentrations (Chongqing, Sichuan,
Guizhou, Anhui and Hunan) were all affected by emissions from the North,
Central and East China, in addition to their local region emissions. In
August, slower northerly and northeasterly wind reduced inter-regional
transport. Nitrate and sulfate concentrations peaked in North China as
dilution was more severely restricted by mountain ranges further north.
Three of the top five high concentration provinces (Tianjin, Hebei and
Beijing) were located in North China and had more than 55\% of local
region contributions. Emissions from North China accounted for similar
to 20\% in the remaining two provinces (Shandong in East China and Henan
in Central China). In addition to emissions from North China, similar to
30\% or more of the nitrate and sulfate concentrations in four of the
top five high concentration provinces (Tianjin, Henan, Hebei and
Shandong) were due to emissions from East China. Time series of daily
regional contributions in three megacities (Beijing, Shanghai and
Chongqing) and a large city cluster (PRD) also indicated stronger and
more frequent inter-regional transport in winter than in summer.
Although the cities were mostly affected by local region emissions,
influences of long range transport were especially obvious for sulfate
concentration in the PRD region in winter, where emissions from North,
East and Central China often accounted for more than 80\% of the total
concentrations. The results from this study suggest that provincial or
region-level emission controls alone may not be sufficient to
effectively reduce nitrate and sulfate concentrations in many areas and
coordinated local and inter-regional emission control strategies are
necessary for the country. (C) 2014 Elsevier Ltd. All rights reserved.}},
Publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}},
Address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}},
Type = {{Article}},
Language = {{English}},
Affiliation = {{Ying, Q (Corresponding Author), Texas A\&M Univ, Zachry Dept Civil Engn, College Stn, TX 77843 USA.
Ying, Qi; Wu, Li, Texas A\&M Univ, Zachry Dept Civil Engn, College Stn, TX 77843 USA.
Zhang, Hongliang, Univ Calif Davis, Dept Civil \& Environm Engn, Davis, CA 95616 USA.}},
DOI = {{10.1016/j.atmosenv.2014.05.078}},
ISSN = {{1352-2310}},
EISSN = {{1873-2844}},
Keywords = {{Secondary particulate matter; Source-oriented air quality model; CMAQ;
Emission source region}},
Keywords-Plus = {{URBAN AIR-POLLUTION; SOURCE APPORTIONMENT; PARTICULATE MATTER; MEGA
CITIES; EAST-ASIA; EMISSIONS; TRANSPORT}},
Research-Areas = {{Environmental Sciences \& Ecology; Meteorology \& Atmospheric Sciences}},
Web-of-Science-Categories = {{Environmental Sciences; Meteorology \& Atmospheric Sciences}},
Author-Email = {{qi.ying@gmail.com}},
ResearcherID-Numbers = {{Zhang, Hongliang/C-2499-2012
}},
ORCID-Numbers = {{Zhang, Hongliang/0000-0002-1797-2311
Ying, Qi/0000-0002-4560-433X}},
Number-of-Cited-References = {{23}},
Times-Cited = {{95}},
Usage-Count-Last-180-days = {{10}},
Usage-Count-Since-2013 = {{205}},
Journal-ISO = {{Atmos. Environ.}},
Doc-Delivery-Number = {{AN1AY}},
Unique-ID = {{WOS:000340316300063}},
DA = {{2021-12-02}},
}
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In January, high concentrations of nitrate (similar to 30 mu g m(-3)) occurred in the North China Plain (NCP) and the Middle and Lower Yangtze Plain (MLYP), as well as the Sichuan Basin. NOx emissions from North, Central and East China were transported over long distances to form rather uniform concentration of nitrate in the NCP and MLYP regions and significantly impacted nitrate concentrations in downwind regions as far as the Pearl River Delta (PRD) region in South China. Wintertime sulfate concentrations demonstrated a more significant inter-regional southward transport pattern and wider spatial distributions than nitrate. The top-five ranked provinces with combined nitrate and sulfate concentrations (Chongqing, Sichuan, Guizhou, Anhui and Hunan) were all affected by emissions from the North, Central and East China, in addition to their local region emissions. In August, slower northerly and northeasterly wind reduced inter-regional transport. Nitrate and sulfate concentrations peaked in North China as dilution was more severely restricted by mountain ranges further north. Three of the top five high concentration provinces (Tianjin, Hebei and Beijing) were located in North China and had more than 55% of local region contributions. Emissions from North China accounted for similar to 20% in the remaining two provinces (Shandong in East China and Henan in Central China). In addition to emissions from North China, similar to 30% or more of the nitrate and sulfate concentrations in four of the top five high concentration provinces (Tianjin, Henan, Hebei and Shandong) were due to emissions from East China. Time series of daily regional contributions in three megacities (Beijing, Shanghai and Chongqing) and a large city cluster (PRD) also indicated stronger and more frequent inter-regional transport in winter than in summer. Although the cities were mostly affected by local region emissions, influences of long range transport were especially obvious for sulfate concentration in the PRD region in winter, where emissions from North, East and Central China often accounted for more than 80% of the total concentrations. The results from this study suggest that provincial or region-level emission controls alone may not be sufficient to effectively reduce nitrate and sulfate concentrations in many areas and coordinated local and inter-regional emission control strategies are necessary for the country. (C) 2014 Elsevier Ltd. All rights reserved.","publisher":"PERGAMON-ELSEVIER SCIENCE LTD","address":"THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND","language":"English","affiliation":"Ying, Q (Corresponding Author), Texas A&M Univ, Zachry Dept Civil Engn, College Stn, TX 77843 USA. Ying, Qi; Wu, Li, Texas A&M Univ, Zachry Dept Civil Engn, College Stn, TX 77843 USA. Zhang, Hongliang, Univ Calif Davis, Dept Civil & Environm Engn, Davis, CA 95616 USA.","doi":"10.1016/j.atmosenv.2014.05.078","issn":"1352-2310","eissn":"1873-2844","keywords":"Secondary particulate matter; Source-oriented air quality model; CMAQ; Emission source region","keywords-plus":"URBAN AIR-POLLUTION; SOURCE APPORTIONMENT; PARTICULATE MATTER; MEGA CITIES; EAST-ASIA; EMISSIONS; TRANSPORT","research-areas":"Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences","web-of-science-categories":"Environmental Sciences; Meteorology & Atmospheric Sciences","author-email":"qi.ying@gmail.com","researcherid-numbers":"Zhang, Hongliang/C-2499-2012 ","orcid-numbers":"Zhang, Hongliang/0000-0002-1797-2311 Ying, Qi/0000-0002-4560-433X","number-of-cited-references":"23","times-cited":"95","usage-count-last-180-days":"10","usage-count-since-2013":"205","journal-iso":"Atmos. 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NOx emissions from North, Central and East China were\n transported over long distances to form rather uniform concentration of\n nitrate in the NCP and MLYP regions and significantly impacted nitrate\n concentrations in downwind regions as far as the Pearl River Delta (PRD)\n region in South China. Wintertime sulfate concentrations demonstrated a\n more significant inter-regional southward transport pattern and wider\n spatial distributions than nitrate. The top-five ranked provinces with\n combined nitrate and sulfate concentrations (Chongqing, Sichuan,\n Guizhou, Anhui and Hunan) were all affected by emissions from the North,\n Central and East China, in addition to their local region emissions. In\n August, slower northerly and northeasterly wind reduced inter-regional\n transport. Nitrate and sulfate concentrations peaked in North China as\n dilution was more severely restricted by mountain ranges further north.\n Three of the top five high concentration provinces (Tianjin, Hebei and\n Beijing) were located in North China and had more than 55\\% of local\n region contributions. Emissions from North China accounted for similar\n to 20\\% in the remaining two provinces (Shandong in East China and Henan\n in Central China). In addition to emissions from North China, similar to\n 30\\% or more of the nitrate and sulfate concentrations in four of the\n top five high concentration provinces (Tianjin, Henan, Hebei and\n Shandong) were due to emissions from East China. Time series of daily\n regional contributions in three megacities (Beijing, Shanghai and\n Chongqing) and a large city cluster (PRD) also indicated stronger and\n more frequent inter-regional transport in winter than in summer.\n Although the cities were mostly affected by local region emissions,\n influences of long range transport were especially obvious for sulfate\n concentration in the PRD region in winter, where emissions from North,\n East and Central China often accounted for more than 80\\% of the total\n concentrations. The results from this study suggest that provincial or\n region-level emission controls alone may not be sufficient to\n effectively reduce nitrate and sulfate concentrations in many areas and\n coordinated local and inter-regional emission control strategies are\n necessary for the country. (C) 2014 Elsevier Ltd. 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