@Article{zagar06sequence,
  author      = {Zagar, Ema and Krzan, Andrej and Adamus, Grazyna and Kowalczuk, Marek},
  title       = {Sequence distribution in microbial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) co-polyesters determined by NMR and MS.},
  journal     = {Biomacromolecules},
  year        = {2006},
  volume      = {7},
  number      = {7},
  pages       = {2210--2216},
  abstract    = {The microstructure of bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolyesters (PHBV) as well as a mixture of two PHBV copolyesters of different comonomer composition and sequence distribution was studied by 13C NMR based on dyad and triad analysis and multistage electrospray ionization mass spectrometry (ESI-MSn). Both techniques gave results that were in good agreement for all investigated samples. The effect of microstructure on PHBV thermal properties was investigated from the melting behavior of samples. A PHBV copolyester with randomly distributed hydroxyvalerate units (12.0 mol \% HV) showed a single melting peak, whereas samples with nonrandom composition distribution showed multiple melting peaks in their thermograms. Such complex melting behavior suggested that the 12.9 and 27.1 mol \% PHBV copolyesters were actually blends of several copolymers with widely different comonomer-unit composition.},
  doi         = {10.1021/bm060201g},
  keywords    = {Calorimetry, Differential Scanning; Cupriavidus necator, chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Polyesters, chemistry; Spectrometry, Mass, Electrospray Ionization; Temperature, polymer ms},
  optmonth    = jul,
  owner       = {martin},
  pmid        = {16827589},
  timestamp   = {2015.03.16},
}

{"_id":"DAjoBHzg4R5BLB5zu","bibbaseid":"zagar-krzan-adamus-kowalczuk-sequencedistributioninmicrobialpoly3hydroxybutyrateco3hydroxyvaleratecopolyestersdeterminedbynmrandms-2006","authorIDs":[],"author_short":["Zagar, E.","Krzan, A.","Adamus, G.","Kowalczuk, M."],"bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Zagar"],"firstnames":["Ema"],"suffixes":[]},{"propositions":[],"lastnames":["Krzan"],"firstnames":["Andrej"],"suffixes":[]},{"propositions":[],"lastnames":["Adamus"],"firstnames":["Grazyna"],"suffixes":[]},{"propositions":[],"lastnames":["Kowalczuk"],"firstnames":["Marek"],"suffixes":[]}],"title":"Sequence distribution in microbial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) co-polyesters determined by NMR and MS.","journal":"Biomacromolecules","year":"2006","volume":"7","number":"7","pages":"2210–2216","abstract":"The microstructure of bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolyesters (PHBV) as well as a mixture of two PHBV copolyesters of different comonomer composition and sequence distribution was studied by 13C NMR based on dyad and triad analysis and multistage electrospray ionization mass spectrometry (ESI-MSn). Both techniques gave results that were in good agreement for all investigated samples. The effect of microstructure on PHBV thermal properties was investigated from the melting behavior of samples. A PHBV copolyester with randomly distributed hydroxyvalerate units (12.0 mol % HV) showed a single melting peak, whereas samples with nonrandom composition distribution showed multiple melting peaks in their thermograms. Such complex melting behavior suggested that the 12.9 and 27.1 mol % PHBV copolyesters were actually blends of several copolymers with widely different comonomer-unit composition.","doi":"10.1021/bm060201g","keywords":"Calorimetry, Differential Scanning; Cupriavidus necator, chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Polyesters, chemistry; Spectrometry, Mass, Electrospray Ionization; Temperature, polymer ms","optmonth":"July","owner":"martin","pmid":"16827589","timestamp":"2015.03.16","bibtex":"@Article{zagar06sequence,\n author = {Zagar, Ema and Krzan, Andrej and Adamus, Grazyna and Kowalczuk, Marek},\n title = {Sequence distribution in microbial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) co-polyesters determined by NMR and MS.},\n journal = {Biomacromolecules},\n year = {2006},\n volume = {7},\n number = {7},\n pages = {2210--2216},\n abstract = {The microstructure of bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolyesters (PHBV) as well as a mixture of two PHBV copolyesters of different comonomer composition and sequence distribution was studied by 13C NMR based on dyad and triad analysis and multistage electrospray ionization mass spectrometry (ESI-MSn). Both techniques gave results that were in good agreement for all investigated samples. The effect of microstructure on PHBV thermal properties was investigated from the melting behavior of samples. A PHBV copolyester with randomly distributed hydroxyvalerate units (12.0 mol \\% HV) showed a single melting peak, whereas samples with nonrandom composition distribution showed multiple melting peaks in their thermograms. Such complex melting behavior suggested that the 12.9 and 27.1 mol \\% PHBV copolyesters were actually blends of several copolymers with widely different comonomer-unit composition.},\n doi = {10.1021/bm060201g},\n keywords = {Calorimetry, Differential Scanning; Cupriavidus necator, chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Polyesters, chemistry; Spectrometry, Mass, Electrospray Ionization; Temperature, polymer ms},\n optmonth = jul,\n owner = {martin},\n pmid = {16827589},\n timestamp = {2015.03.16},\n}\n\n","author_short":["Zagar, E.","Krzan, A.","Adamus, G.","Kowalczuk, M."],"key":"zagar06sequence","id":"zagar06sequence","bibbaseid":"zagar-krzan-adamus-kowalczuk-sequencedistributioninmicrobialpoly3hydroxybutyrateco3hydroxyvaleratecopolyestersdeterminedbynmrandms-2006","role":"author","urls":{},"keyword":["Calorimetry","Differential Scanning; Cupriavidus necator","chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Polyesters","chemistry; Spectrometry","Mass","Electrospray Ionization; Temperature","polymer ms"],"metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"https://git.bio.informatik.uni-jena.de/fleisch/literature/raw/master/group-literature.bib","creationDate":"2019-11-19T16:50:42.896Z","downloads":0,"keywords":["calorimetry","differential scanning; cupriavidus necator","chemistry; magnetic resonance spectroscopy; molecular structure; polyesters","chemistry; spectrometry","mass","electrospray ionization; temperature","polymer ms"],"search_terms":["sequence","distribution","microbial","poly","hydroxybutyrate","hydroxyvalerate","polyesters","determined","nmr","zagar","krzan","adamus","kowalczuk"],"title":"Sequence distribution in microbial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) co-polyesters determined by NMR and MS.","year":2006,"dataSources":["C5FtkvWWggFfMJTFX"]}