Non-aqueous solvents for DNP surface enhanced NMR spectroscopy. Zagdoun, A., Rossini, A. J, Gajan, D., Bourdolle, A., Ouari, O., Rosay, M., Maas, W. E, Tordo, P., Lelli, M., Emsley, L., Lesage, A., & Copéret, C. Chemical communications (Cambridge, England), 48(5):654–656, January, 2012.
Paper doi abstract bibtex A series of non-aqueous solvents combined with the exogenous biradical bTbK are developed for DNP NMR that yield enhancements comparable to the best available water based systems. 1,1,2,2-tetrachloroethane appears to be one of the most promising organic solvents for DNP solid-state NMR. Here this results in a reduction in experimental times by a factor of 1000. These new solvents are demonstrated with the first DNP surface enhanced NMR characterization of an organometallic complex supported on a hydrophobic surface.
@article{Zagdoun2012,
title = {Non-aqueous solvents for {DNP} surface enhanced {NMR} spectroscopy.},
volume = {48},
issn = {1364-548X},
url = {http://www.ncbi.nlm.nih.gov/pubmed/22034623},
doi = {10.1039/c1cc15242d},
abstract = {A series of non-aqueous solvents combined with the exogenous biradical bTbK are developed for DNP NMR that yield enhancements comparable to the best available water based systems. 1,1,2,2-tetrachloroethane appears to be one of the most promising organic solvents for DNP solid-state NMR. Here this results in a reduction in experimental times by a factor of 1000. These new solvents are demonstrated with the first DNP surface enhanced NMR characterization of an organometallic complex supported on a hydrophobic surface.},
number = {5},
urldate = {2013-12-17},
journal = {Chemical communications (Cambridge, England)},
author = {Zagdoun, Alexandre and Rossini, Aaron J and Gajan, David and Bourdolle, Adrien and Ouari, Olivier and Rosay, Melanie and Maas, Werner E and Tordo, Paul and Lelli, Moreno and Emsley, Lyndon and Lesage, Anne and Copéret, Christophe},
month = jan,
year = {2012},
pmid = {22034623},
pages = {654--656},
}
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