Synthesis and crystal structure of a palladium(II) complex with the amino acid L-citrulline. Mascaliovas, B. Z., Bergamini, F. R., Cuin, A., & Corbi, P. P. Powder Diffraction, 30(4):357–361, December, 2015.
Synthesis and crystal structure of a palladium(II) complex with the amino acid L-citrulline [link]Paper  doi  abstract   bibtex   
Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C 6 H 13 N 3 O 3 ) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC 12 H 24 N 6 O 6. The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters a = 4.6493(4) Å, b = 5.222(4) Å, c = 18.040(2) Å, α = 77.41(6)°, β = 94.72(7),° and γ = 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.
@article{mascaliovas_synthesis_2015,
	title = {Synthesis and crystal structure of a palladium({II}) complex with the amino acid {L}-citrulline},
	volume = {30},
	copyright = {https://www.cambridge.org/core/terms},
	issn = {0885-7156, 1945-7413},
	url = {https://www.cambridge.org/core/product/identifier/S0885715615000652/type/journal_article},
	doi = {10.1017/S0885715615000652},
	abstract = {Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C
              6
              H
              13
              N
              3
              O
              3
              ) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC
              12
              H
              24
              N
              6
              O
              6.
              The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters
              a
              = 4.6493(4) Å,
              b
              = 5.222(4) Å,
              c
              = 18.040(2) Å,
              α
              = 77.41(6)°,
              β
              = 94.72(7),° and
              γ
              = 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.},
	language = {en},
	number = {4},
	urldate = {2024-10-24},
	journal = {Powder Diffraction},
	author = {Mascaliovas, Bruno Z. and Bergamini, Fernando R.G. and Cuin, Alexandre and Corbi, Pedro P.},
	month = dec,
	year = {2015},
	pages = {357--361},
}

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