Synthesis and crystal structure of a palladium(II) complex with the amino acid L-citrulline. Mascaliovas, B. Z., Bergamini, F. R., Cuin, A., & Corbi, P. P. Powder Diffraction, 30(4):357–361, December, 2015. Paper doi abstract bibtex Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C 6 H 13 N 3 O 3 ) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC 12 H 24 N 6 O 6. The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters a = 4.6493(4) Å, b = 5.222(4) Å, c = 18.040(2) Å, α = 77.41(6)°, β = 94.72(7),° and γ = 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.
@article{mascaliovas_synthesis_2015,
title = {Synthesis and crystal structure of a palladium({II}) complex with the amino acid {L}-citrulline},
volume = {30},
copyright = {https://www.cambridge.org/core/terms},
issn = {0885-7156, 1945-7413},
url = {https://www.cambridge.org/core/product/identifier/S0885715615000652/type/journal_article},
doi = {10.1017/S0885715615000652},
abstract = {Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C
6
H
13
N
3
O
3
) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC
12
H
24
N
6
O
6.
The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters
a
= 4.6493(4) Å,
b
= 5.222(4) Å,
c
= 18.040(2) Å,
α
= 77.41(6)°,
β
= 94.72(7),° and
γ
= 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.},
language = {en},
number = {4},
urldate = {2024-10-24},
journal = {Powder Diffraction},
author = {Mascaliovas, Bruno Z. and Bergamini, Fernando R.G. and Cuin, Alexandre and Corbi, Pedro P.},
month = dec,
year = {2015},
pages = {357--361},
}
Downloads: 0
{"_id":"qeaZwFMaQ5NR49f5r","bibbaseid":"mascaliovas-bergamini-cuin-corbi-synthesisandcrystalstructureofapalladiumiicomplexwiththeaminoacidlcitrulline-2015","downloads":0,"creationDate":"2017-04-06T15:19:19.886Z","title":"Synthesis and crystal structure of a palladium(II) complex with the amino acid L-citrulline","author_short":["Mascaliovas, B. Z.","Bergamini, F. R.","Cuin, A.","Corbi, P. P."],"year":2015,"bibtype":"article","biburl":"https://api.zotero.org/users/1360635/collections/D6QTG5L9/items?key=M1LYgnALYcuEPooCBFXCVgWF&format=bibtex&limit=100","bibdata":{"bibtype":"article","type":"article","title":"Synthesis and crystal structure of a palladium(II) complex with the amino acid L-citrulline","volume":"30","copyright":"https://www.cambridge.org/core/terms","issn":"0885-7156, 1945-7413","url":"https://www.cambridge.org/core/product/identifier/S0885715615000652/type/journal_article","doi":"10.1017/S0885715615000652","abstract":"Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C 6 H 13 N 3 O 3 ) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC 12 H 24 N 6 O 6. The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters a = 4.6493(4) Å, b = 5.222(4) Å, c = 18.040(2) Å, α = 77.41(6)°, β = 94.72(7),° and γ = 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.","language":"en","number":"4","urldate":"2024-10-24","journal":"Powder Diffraction","author":[{"propositions":[],"lastnames":["Mascaliovas"],"firstnames":["Bruno","Z."],"suffixes":[]},{"propositions":[],"lastnames":["Bergamini"],"firstnames":["Fernando","R.G."],"suffixes":[]},{"propositions":[],"lastnames":["Cuin"],"firstnames":["Alexandre"],"suffixes":[]},{"propositions":[],"lastnames":["Corbi"],"firstnames":["Pedro","P."],"suffixes":[]}],"month":"December","year":"2015","pages":"357–361","bibtex":"@article{mascaliovas_synthesis_2015,\n\ttitle = {Synthesis and crystal structure of a palladium({II}) complex with the amino acid {L}-citrulline},\n\tvolume = {30},\n\tcopyright = {https://www.cambridge.org/core/terms},\n\tissn = {0885-7156, 1945-7413},\n\turl = {https://www.cambridge.org/core/product/identifier/S0885715615000652/type/journal_article},\n\tdoi = {10.1017/S0885715615000652},\n\tabstract = {Synthesis and structural characterization of a novel palladium Pd(II) complex with the amino acid L-citrulline (Cit, C\n 6\n H\n 13\n N\n 3\n O\n 3\n ) are presented in this paper. Elemental analysis indicates a 1:2 metal/ligand molar composition for the complex, with the molecular formula PdC\n 12\n H\n 24\n N\n 6\n O\n 6.\n The compound was also characterized by infrared (IR) spectroscopic measurements and the crystal structure has been solved by powder X-ray diffraction data with simulated annealing strategy in real space. The Pd(II) complex crystallizes in the triclinic system with space group P-1 and cell parameters\n a\n = 4.6493(4) Å,\n b\n = 5.222(4) Å,\n c\n = 18.040(2) Å,\n α\n = 77.41(6)°,\n β\n = 94.72(7),° and\n γ\n = 101.45(7)°. The crystal structure confirms the presence of Pd(II) ions in a nearly square planar environment and the molecular formula with deprotonated citrulline as proposed by analytical and spectroscopic data.},\n\tlanguage = {en},\n\tnumber = {4},\n\turldate = {2024-10-24},\n\tjournal = {Powder Diffraction},\n\tauthor = {Mascaliovas, Bruno Z. and Bergamini, Fernando R.G. and Cuin, Alexandre and Corbi, Pedro P.},\n\tmonth = dec,\n\tyear = {2015},\n\tpages = {357--361},\n}\n\n","author_short":["Mascaliovas, B. Z.","Bergamini, F. R.","Cuin, A.","Corbi, P. P."],"key":"mascaliovas_synthesis_2015","id":"mascaliovas_synthesis_2015","bibbaseid":"mascaliovas-bergamini-cuin-corbi-synthesisandcrystalstructureofapalladiumiicomplexwiththeaminoacidlcitrulline-2015","role":"author","urls":{"Paper":"https://www.cambridge.org/core/product/identifier/S0885715615000652/type/journal_article"},"metadata":{"authorlinks":{"bergamini, f":"https://bibbase.org/service/mendeley/6d4e9e22-09e3-3340-83ee-25b0de1090e1/group/edb17a89-a16c-3c5d-8f2a-ce318aa08fb4","corbi, p":"https://bibbase.org/service/mendeley/12b9f049-9566-3679-935b-c90c226950d2/group/90e2c5d9-8e7e-3658-9751-f62154fc0a37"}},"downloads":0},"search_terms":["synthesis","crystal","structure","palladium","complex","amino","acid","citrulline","mascaliovas","bergamini","cuin","corbi"],"keywords":[],"authorIDs":["58d52ba1d55adc3b7e000060","5b5ce875b81c1a10000000a0","5de99c8b59feb7f201000136","5df826d9dc1981de0100003d","5e3a92060b62daf3010000db","5e3abcc0f2a00cdf010000a5","CPEZPKqGGQkwNkELA","JveZ7r6HFmq6jH9Rg","Sx9sf7isPQDungGX5","kN7dkm3HZZNz2jgoG","m3HgPrLB3PrXd3Nad","mS7DnCgD5mEBXaoft","n8rttPMWNGRoNPQqv","pQoxpzZ2W6JpaQXPf"],"dataSources":["qshhWLKQydZqDJekD","ya2CyA73rpZseyrZ8","2252seNhipfTmjEBQ","8JzyX5ddx5f6obrhn","o2mL7kG99iAQPpNRJ"]}