@article{
 title = {Silver(I) complexes with symmetrical Schiff bases: Synthesis, structural characterization, DFT studies and antimycobacterial assays},
 type = {article},
 year = {2013},
 keywords = {Mycobacterium,Schiff bases,Silver,[Anisaldehyde},
 volume = {62},
 id = {8ad49530-b708-3cb0-b4f8-4598b7265db7},
 created = {2018-07-28T23:28:38.665Z},
 file_attached = {false},
 profile_id = {6d4e9e22-09e3-3340-83ee-25b0de1090e1},
 group_id = {edb17a89-a16c-3c5d-8f2a-ce318aa08fb4},
 last_modified = {2018-07-28T23:28:38.665Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {Paiva2013},
 source_type = {article},
 private_publication = {false},
 abstract = {Synthesis, structural and spectroscopic characterizations, molecular modeling and antimycobacterial assays of new silver(I) complexes with two Schiff bases - MBDA and MBDB - are reported. The complexes [Ag(MBDA) 2]NO3, or AgMBDA, and [Ag(MBDB)NO3] or AgMBDB, were obtained by the reaction of the respective ligands with silver(I) nitrate in methanol. The Schiff bases were previously obtained by mixing ethylenediamine or 1,3-diaminopropane with p-anisaldehyde. The characterizations of the complexes were based on elemental (C, H and N) and thermal (TG-DTA) analyses and 13C and 1H NMR and FT-IR spectroscopic measurements, as well as X-ray structure determination for AgMBDA. Spectroscopic data predicted by DFT calculations are in agreement with the experimental data for the AgMBDA complex. The AgMBDA complex has a monomeric structure with a molar proportion 1:2 Ag/ligand, while AgMBDB presents a 1:1 proportion. The complexes AgMBDA and AgMBDB showed to be more effective against Mycobacterium tuberculosis than antibacterial agent silver sulfadiazine - SSD. ©2013 Elsevier Ltd. All rights reserved.},
 bibtype = {article},
 author = {Paiva, I L and De Carvalho, G S G and Da Silva, A D and Corbi, P P and Bergamini, F R G and Formiga, A L B and Diniz, R and Do Carmo, W R and Leite, C Q F and Pavan, F R and Cuin, A},
 doi = {10.1016/j.poly.2013.06.031},
 journal = {Polyhedron}
}

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The complexes [Ag(MBDA) 2]NO3, or AgMBDA, and [Ag(MBDB)NO3] or AgMBDB, were obtained by the reaction of the respective ligands with silver(I) nitrate in methanol. The Schiff bases were previously obtained by mixing ethylenediamine or 1,3-diaminopropane with p-anisaldehyde. The characterizations of the complexes were based on elemental (C, H and N) and thermal (TG-DTA) analyses and 13C and 1H NMR and FT-IR spectroscopic measurements, as well as X-ray structure determination for AgMBDA. Spectroscopic data predicted by DFT calculations are in agreement with the experimental data for the AgMBDA complex. The AgMBDA complex has a monomeric structure with a molar proportion 1:2 Ag/ligand, while AgMBDB presents a 1:1 proportion. The complexes AgMBDA and AgMBDB showed to be more effective against Mycobacterium tuberculosis than antibacterial agent silver sulfadiazine - SSD. ©2013 Elsevier Ltd. All rights reserved.","bibtype":"article","author":"Paiva, I L and De Carvalho, G S G and Da Silva, A D and Corbi, P P and Bergamini, F R G and Formiga, A L B and Diniz, R and Do Carmo, W R and Leite, C Q F and Pavan, F R and Cuin, A","doi":"10.1016/j.poly.2013.06.031","journal":"Polyhedron","bibtex":"@article{\n title = {Silver(I) complexes with symmetrical Schiff bases: Synthesis, structural characterization, DFT studies and antimycobacterial assays},\n type = {article},\n year = {2013},\n keywords = {Mycobacterium,Schiff bases,Silver,[Anisaldehyde},\n volume = {62},\n id = {8ad49530-b708-3cb0-b4f8-4598b7265db7},\n created = {2018-07-28T23:28:38.665Z},\n file_attached = {false},\n profile_id = {6d4e9e22-09e3-3340-83ee-25b0de1090e1},\n group_id = {edb17a89-a16c-3c5d-8f2a-ce318aa08fb4},\n last_modified = {2018-07-28T23:28:38.665Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {Paiva2013},\n source_type = {article},\n private_publication = {false},\n abstract = {Synthesis, structural and spectroscopic characterizations, molecular modeling and antimycobacterial assays of new silver(I) complexes with two Schiff bases - MBDA and MBDB - are reported. The complexes [Ag(MBDA) 2]NO3, or AgMBDA, and [Ag(MBDB)NO3] or AgMBDB, were obtained by the reaction of the respective ligands with silver(I) nitrate in methanol. The Schiff bases were previously obtained by mixing ethylenediamine or 1,3-diaminopropane with p-anisaldehyde. The characterizations of the complexes were based on elemental (C, H and N) and thermal (TG-DTA) analyses and 13C and 1H NMR and FT-IR spectroscopic measurements, as well as X-ray structure determination for AgMBDA. Spectroscopic data predicted by DFT calculations are in agreement with the experimental data for the AgMBDA complex. The AgMBDA complex has a monomeric structure with a molar proportion 1:2 Ag/ligand, while AgMBDB presents a 1:1 proportion. The complexes AgMBDA and AgMBDB showed to be more effective against Mycobacterium tuberculosis than antibacterial agent silver sulfadiazine - SSD. ©2013 Elsevier Ltd. 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